Electrode reactions of manganese oxides for secondary lithium batteries

被引：258

作者：

Fang, Xiangpeng ^{[1
]}

Lu, Xia ^{[1
]}

Guo, Xianwei ^{[1
]}

Mao, Ya ^{[1
]}

Hu, Yong-Sheng ^{[1
]}

Wang, Jiazhao ^{[2
]}

Wang, Zhaoxiang ^{[1
]}

Wu, Feng ^{[3
]}

Liu, Huakun ^{[2
]}

Chen, Liquan ^{[1
,4
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Lab Solid State Ion, Beijing 100190, Peoples R China

[2] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2252, Australia

[3] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[4] Chonnam Natl Univ, Sch Mat Sci & Engn, Gwanju 500757, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 11期

基金：

美国国家科学基金会;

关键词：

Structural evolution; Manganese oxides; Electrode material; Lithium batteries; Metallic Mn;

D O I：

10.1016/j.elecom.2010.08.023

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Nanorods of MnO2, Mn3O4, Mn2O3 and MnO are synthesized by hydrothermal reactions and subsequent annealing. It is shown that though different oxides experience distinct phase transition processes in the initial discharge, metallic Mn and Li2O are the end products of discharge, while MnO is the end product of recharge for all these oxides between 0.0 and 3.0 V vs. Li+/Li. Of these 4 manganese oxides, MnO is believed the most promising anode material for lithium ion batteries while MnO2 is the most promising cathode material for secondary lithium batteries. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1520 / 1523

页数：4

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