Electrode reactions of manganese oxides for secondary lithium batteries

被引：256

作者：

Fang, Xiangpeng ^{[1
]}

Lu, Xia ^{[1
]}

Guo, Xianwei ^{[1
]}

Mao, Ya ^{[1
]}

Hu, Yong-Sheng ^{[1
]}

Wang, Jiazhao ^{[2
]}

Wang, Zhaoxiang ^{[1
]}

Wu, Feng ^{[3
]}

Liu, Huakun ^{[2
]}

Chen, Liquan ^{[1
,4
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Lab Solid State Ion, Beijing 100190, Peoples R China

[2] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2252, Australia

[3] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[4] Chonnam Natl Univ, Sch Mat Sci & Engn, Gwanju 500757, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 11期

基金：

美国国家科学基金会;

关键词：

Structural evolution; Manganese oxides; Electrode material; Lithium batteries; Metallic Mn;

D O I：

10.1016/j.elecom.2010.08.023

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Nanorods of MnO2, Mn3O4, Mn2O3 and MnO are synthesized by hydrothermal reactions and subsequent annealing. It is shown that though different oxides experience distinct phase transition processes in the initial discharge, metallic Mn and Li2O are the end products of discharge, while MnO is the end product of recharge for all these oxides between 0.0 and 3.0 V vs. Li+/Li. Of these 4 manganese oxides, MnO is believed the most promising anode material for lithium ion batteries while MnO2 is the most promising cathode material for secondary lithium batteries. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1520 / 1523

页数：4

共 11 条

[1] Some new facts on electrochemical reaction mechanism for transition metal oxide electrodes
Chen, Chunhua
Ding, Ning
Wang, Long
Yu, Yan
Lieberwirth, Ingo
[J]. JOURNAL OF POWER SOURCES, 2009, 189 (01) : 552 - 556
[2] Electrospun manganese oxide nanofibers as anodes for lithium-ion batteries
Fan, Quan
Whittingham, M. Stanley
[J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (03) : A48 - A51
[3] Nano-Sn/hard carbon composite anode material with high-initial coulombic efficiency
Guo, Bingkun
Shu, Jie
Tang, Kun
Bai, Ying
Wang, Zhaoxiang
Chen, Liquan
[J]. JOURNAL OF POWER SOURCES, 2008, 177 (01) : 205 - 210
[4] Lithium storage in hollow spherical ZnFe2O4 as anode materials for lithium ion batteries
Guo, Xianwei
Lu, Xia
Fang, Xiangpeng
Mao, Ya
Wang, Zhaoxiang
Chen, Liquan
Xu, Xiaoxue
Yang, Hong
Liu, Yinong
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (06) : 847 - 850
[5] High lithium electroactivity of nanometer-sized rutile TiO2
Hu, Yong-Sheng
Kienle, Lorenz
Guo, Yu- Guo
Maier, Joachim
[J]. ADVANCED MATERIALS, 2006, 18 (11) : 1421 - +
[6] Electronic structure of C84 film studied by photoemission measurement and first-principles calculation
Li, Hong-Nian
Yang, Hua
Wang, Xiao-Xiong
Ni, Jing-Fu
Wang, Peng
Meng, Liang
Wang, Xiao-Bo
Kurash, Ibrahim
Qian, Hai-Jie
Wang, Jia-Ou
Liu, Zi-Yang
[J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2009, 21 (26)
[7] *P ELM CORP PHYS E, HDB XRAY PHOT SPECTR
[8] Nano-sized transition-metaloxides as negative-electrode materials for lithium-ion batteries
Poizot, P
Laruelle, S
Grugeon, S
Dupont, L
Tarascon, JM
[J]. NATURE, 2000, 407 (6803) : 496 - 499
[9] Coaxial MnO2/Carbon Nanotube Array Electrodes for High-Performance Lithium Batteries
Reddy, Arava Leela Mohana
Shaijumon, Manikoth M.
Gowda, Sanketh R.
Ajayan, Pulickel M.
[J]. NANO LETTERS, 2009, 9 (03) : 1002 - 1006
[10] Influence of Size on the Rate of Mesoporous Electrodes for Lithium Batteries
Ren, Yu
Armstrong, A. Robert
Jiao, Feng
Bruce, Peter G.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) : 996 - 1004

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