Nitrogen atom transfer between manganese complexes of salen, porphyrin, and corrole and characterization of a (nitrido)manganese(VI) corrole

被引：76
|
作者：
Golubkov, G
Gross, Z [1 ]
机构：
[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel
[2] Technion Israel Inst Technol, Inst Catalysis Sci, IL-32000 Haifa, Israel
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 10期
关键词：
D O I：
10.1021/ja043683h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The investigations of complete nitrogen atom transfer reactions from (nitrido)manganese(V) salen to manganese(III) complexes of porphyrins and corroles revealed that stabilization of the [Mn(N)]2+ moiety is in the order of corrole > porphyrin ≫ salen. The first kinetic examination of this quite fundamental reaction exposed a large solvent effect on both the enthalpy and entropy activation energies. Oxidation of the (nitrido)manganese(V) corroles leads to the first (nitrido)manganese(VI) complexes that are coordinated by tetrapyrrolic ligands. Copyright © 2005 American Chemical Society.
引用
收藏
页码：3258 / 3259
页数：2
相关论文
共 50 条
  • [1] High-valent iron and manganese complexes of corrole and porphyrin in atom transfer and dioxygen evolving catalysis
    Abu-Omar, Mahdi M.
    DALTON TRANSACTIONS, 2011, 40 (14) : 3435 - 3444
  • [2] Oxygen Atom Transfer Reaction Mechanism between Manganese(V)-Oxo Corrole Complexes and Styrene
    Zeng Qi
    Xu Yan
    Chen Hua-Bin
    Xu Xuan
    Xu Zhi-Guang
    Liu Hai-Yang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2022, 38 (01) : 39 - 45
  • [3] Manganese complexes of a novel corrole.
    Bendix, J
    Golubkov, G
    Gross, Z
    Gray, HB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U815 - U815
  • [4] A tris-(manganese(iii))corrole-porphyrin-corrole triad: synthesis, characterization and catalytic epoxidation
    Rai, Jyoti
    Basumatary, Biju
    Bhandary, Subhrajyoti
    Murugavel, Muthuchamy
    Sankar, Jeyaraman
    DALTON TRANSACTIONS, 2019, 48 (21) : 7394 - 7402
  • [5] Hydrogen atom transfer to high valent manganese(V) imido corrole
    Dexheimer, Jennifer L.
    Zdilla, Michael J.
    Abu-Omar, Mahdi M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 651 - 651
  • [6] Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene
    Lan Yu
    Qi Wang
    Lu Dai
    Wei-Ying Li
    Rong Chen
    Mian HR Mahmood
    Hai-Yang Liu
    Chi-Kwong Chang
    Chinese Chemical Letters, 2013, 24 (06) : 447 - 449
  • [7] Solvent effects on oxygen atom transfer reaction between manganese(V)-oxo corrole and alkene
    Yu, Lan
    Wang, Qi
    Dai, Lu
    Li, Wei-Ying
    Chen, Rong
    Mahmood, Mian H. R.
    Liu, Hai-Yang
    Chang, Chi-Kwong
    CHINESE CHEMICAL LETTERS, 2013, 24 (06) : 447 - 449
  • [8] Chromium(V) and chromium(VI) nitrido complexes of tris(pentafluorophenyl)corrole
    Golubkov, G
    Gross, Z
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (37) : 4507 - 4510
  • [9] Visible-light photolysis of corrole-manganese(IV) nitrites to generate corrole-manganese(V)-oxo complexes
    Lee, Ngo Fung
    Malone, Jonathan
    Jeddi, Haleh
    Kwong, Ka Wai
    Zhang, Rui
    INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 82 : 27 - 30
  • [10] Nitrogen atom transfer from manganese(V)nitrido to rhenium(III) complexes.
    Eikey, RA
    Abu-Omar, M
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U670 - U670
12345