Nickel-catalyzed C-P cross-coupling of (het)aryl tosylates with secondary phosphine oxides

被引：3

作者：

He, Xiao-Yun ^{[1
]}

机构：

[1] Hebei Chem & Pharmaceut Coll, Dept Chem & Environm Engn, Shijiazhuang 050026, Hebei, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2021年 / 45卷 / 7-8期

关键词：

C-P bond; (het)aromatic tosylates; nickel-catalyzed; phosphorylation; tertiary phosphine oxides; BOND FORMATION; ARYLBORONIC ACIDS; PHOSPHORYLATION; NUCLEOPHILES; DERIVATIVES; AMINATION; ALKYNES; LIGAND;

D O I：

10.1177/1747519821994533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel and convenient approach to the synthesis of various tertiary phosphine oxides via nickel-catalyzed cross-coupling of (het)aromatic tosylates with secondary phosphine oxides is developed. The reaction employs cheap nickel as the catalyst, 1-(2-(di-tert-butylphosphanyl)phenyl)-4-methoxypiperidine (L3) as the ligand, and pyridine as the base. This reaction produces the corresponding (het)aromatic phosphorus compounds in good to high yields. Moreover, four new tertiary phosphine oxides are reported in this process.

引用

页码：747 / 752

页数：6

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