Alkyl-chain dividing layer at an alcohol/ionic liquid buried interface studied by sum-frequency generation vibrational spectroscopy

被引：19
作者：
Iwahashi, Takashi [1 ,2 ]
Sakai, Yasunari [1 ]
Kanai, Kaname [1 ]
Kim, Doseok [3 ]
Ouchi, Yukio [1 ]
机构：
[1] Nagoya Univ, Dept Chem, Grad Sch Sci, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, VBL, Nagoya, Aichi 4648603, Japan
[3] Sogang Univ, Dept Phys, Seoul 121742, South Korea
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 40期
关键词：
IONIC LIQUIDS; AIR/LIQUID INTERFACE; STRETCHING MODES; WATER-INTERFACE; LOCAL-STRUCTURE; SIMULATIONS; ADSORPTION; CRYSTALS; SURFACES; SI(100);
D O I：
10.1039/c0cp00520g
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We demonstrate for the first time the formation of a non-polar alkyl-chain dividing layer between a room-temperature ionic liquid (RTIL) and an n-alcohol. This newly described non-polar interfacial layer, which should be more hydrophobic than both RTIL and alcohol phases, might find applications in liquid/liquid reaction systems, or serve as a soft nano-functional space.
引用
收藏
页码：12943 / 12946
页数：4
相关论文
共 50 条
  • [21] Choose your own adventure: Picosecond or broadband vibrational sum-frequency generation spectroscopy
    Carpenter, Andrew P.
    Baio, Joe E.
    BIOINTERPHASES, 2022, 17 (03)
  • [22] Molecular Orientation of Carboxylate Anions at the Water-Air Interface Studied with Heterodyne-Detected Vibrational Sum-Frequency Generation
    Korotkevich, Alexander A.
    Moll, Carolyn J.
    Versluis, Jan
    Bakker, Huib J.
    JOURNAL OF PHYSICAL CHEMISTRY B, 2023, 127 (20) : 4544 - 4553
  • [23] Observation of Charge Inversion of an Ionic Liquid at the Solid Salt-Liquid Interface by Sum Frequency Generation Spectroscopy
    Penalber, Chariz Y.
    Baldelli, Steven
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (07): : 844 - 847
  • [24] The mechanism of alkyl ketene dimer (AKD) sizing on cellulose model films studied by sum frequency generation vibrational spectroscopy
    Li, Lei
    Neivandt, David J.
    CELLULOSE, 2019, 26 (05) : 3415 - 3435
  • [25] Impact of intermolecular vibrational coupling effects on the sum-frequency generation spectra of the water/air interface
    Kaliannan, Naveen Kumar
    Aristizabal, Andres Henao
    Wiebeler, Hendrik
    Zysk, Frederik
    Ohto, Tatsuhiko
    Nagata, Yuki
    Kuehne, Thomas D.
    MOLECULAR PHYSICS, 2020, 118 (04)
  • [26] Flexible high-resolution broadband sum-frequency generation vibrational spectroscopy for intrinsic spectral line widths
    Zhang, Ruidan
    Peng, Xingxing
    Jiao, Zhirun
    Luo, Ting
    Zhou, Chuanyao
    Yang, Xueming
    Ren, Zefeng
    JOURNAL OF CHEMICAL PHYSICS, 2019, 150 (07)
  • [27] Sum Frequency Generation Vibrational Spectroscopy Study of Serial Short Chain Fatty Acids Liquid/Air Interfaces
    Huang Zhi
    Guo Yuan
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2012, 33 (06): : 1271 - 1277
  • [28] Structure and charging of hydrophobic material/water interfaces studied by phase-sensitive sum-frequency vibrational spectroscopy
    Tian, C. S.
    Shen, Y. R.
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (36) : 15148 - 15153
  • [29] Reversible photoisomerization of an azobenzene-functionalized self-assembled monolayer probed by sum-frequency generation vibrational spectroscopy
    Wagner, Steffen
    Leyssner, Felix
    Koerdel, Christian
    Zarwell, Sebastian
    Schmidt, Roland
    Weinelt, Martin
    Rueck-Braun, Karola
    Wolf, Martin
    Tegeder, Petra
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (29) : 6242 - 6248
  • [30] The Structure of Oleamide Films at the Aluminum/Oil Interface and Aluminum/Air Interface Studied by Sum Frequency Generation (SFG) Vibrational Spectroscopy and Reflection Absorption Infrared Spectroscopy (RAIRS)
    Casford, Michael T. L.
    Davies, Paul B.
    ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (08) : 1672 - 1681
12345