Rational design of unique graphene modified cobalt manganite hollow microcubes for supercapacitors

被引:10
作者
Li, Hongwei [1 ]
Lin, Liyang [1 ]
Zhao, Qiannan [1 ]
Xu, Chaohe [1 ]
Peng, Xianghe [1 ]
Hu, Ning [1 ,2 ,3 ]
机构
[1] Chongqing Univ, Coll Aerosp Engn, Chongqing 400044, Peoples R China
[2] Chongqing Univ, Key Disciplines Lab Novel Micronano Devices & Sys, Chongqing 400044, Peoples R China
[3] Chongqing Univ, Int R&D Ctr Micronano Syst & New Mat Technol, Chongqing 400044, Peoples R China
关键词
Hollow microcubes; Graphene; Electrochemical performance; Specific capacitance; HIGH-PERFORMANCE; FACILE SYNTHESIS; COMN2O4; MICROSPHERES; CARBON; OXIDE; NANORODS; ARRAYS; ENERGY;
D O I
10.1016/j.apsusc.2018.07.217
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel reduced graphene oxide (rGO) modified ternary metal oxide electrode material with rational microstructure was successfully developed by the hydrothermal approach following the heat treatment, in which gauze-like rGO sheets were homogeneously decorated on the surfaces of uniform CoMn2O4 hollow microcubes. Benefitting from this special hybrid morphology possessing large specific surface area and good conductivity, the CoMn2O4@rGO composite gave rise to a greater specific capacitance of 1194.7 F g(-1) at a low current density of 2 mA cm(-2), longer cycle life (88.6% capacitance retention after 5000 cycles), and more excellent rate performance when fabricated into a promising electrode for electrochemical supercapacitors.
引用
收藏
页码:16 / 22
页数:7
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