Experimental investigation of large-ion-lithophile-element-, high-field-strength-element- and rare-earth-element-partitioning between calcic amphibole and basaltic melt:: the effects of pressure and oxygen fugacity

The effects of pressure and oxygen fugacity (fO(2)) on trace element partitioning between pargasitic amphibole and alkali-basaltic melts have been determined at pressures from 1.5 to 2.5 GPa and oxygen fugacities at 2 log units above and below the nickel-nickel oxide buffer. Amphibole crystallization experiments were performed in a piston cylinder apparatus and partition coefficients between amphibole and quenched melt of large-ion-lithophile elements (LILE: Rb, Sr, Ba), high-field-strength elements (HFSE: Zr, Nb, Ta, Hf U, Th) and rare-earth elements (REE: La to Lu; + Y) were measured with a LASER ablation inductively coupled plasma - mass spectrometer. Increasing pressure from 1.5 to 2.5 GPa at similar temperatures and approximately constant fO(2) increases D-Rb but decreases D-Zr and D-Hf and D-REE (D-La, D-Ce, D-Pr) An empirical relationship was observed between D-Zr and (Ti/Al)(M2) in the amphibole, which can be described by: Log D-Zr = 0.5323 x log (Ti/Al)(M2) - 1.5924 Increasing the fO(2) by similar to4 log units (similar to NNO-2.0 to similar to NNO + 2.2) at similar temperatures and constant pressure increases D-Ba and D-Nd but decreases D-Ti An increase in pressure or fO(2) decreases the maximum partition coefficient (D-0), the Young's modulus (E) and the optimum ionic radius (r(0)) of the A-, M2- and M4-lattice sites. The calculated r(0) values from the monovalent cations (Na, K, Rb) in the A site and the quadrivalent cations (Ti, Hf, Zr) in the M2 lattice sites suggests that amphiboles crystallized from alkaline basalt material have smaller [A-O] and [M2-O], mean bond-lengths than those formed from pargasitic materials at identical pressures and fO(2)'s The measured partition coefficients were used to calculate trace element concentrations in melts formed by partial melting of amphibole-bearing peridotite. This modeling demonstrates those changes in either the pressure or fO(2) Of melting can exert a significant effect on Rb/HFSE ratios in the melts and thus help explain the wide variations of these ratios sometimes observed in basaltic rock suites.