A new 2D Co5-cluster based MOF: Crystal structure, magnetic properties and electrocatalytic hydrogen evolution reaction

被引：25
|
作者：
Tian, Jun-Wu [1 ]
Fu, Meng-Xi [2 ]
Huang, Dan-Dan [1 ]
Wang, Xiao-Kun [1 ]
Wu, Ya-Pan [1 ]
Lu, Jack Y. [3 ]
Li, Dong-Sheng [1 ]
机构：
[1] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Peoples R China
[2] Xian Technol Univ, Sch Mat Sci & Chem Engn, Xian 710072, Shaanxi, Peoples R China
[3] Univ Houstons Clear Lake, Dept Chem, Houston, TX 77058 USA
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 95卷
关键词：
3,5-bis(3 '-carboxyphenyl)-1,2,4-triazole; Co-MOF; Crystal structure; Magnetic properties; Hydrogen evolution reaction; METAL-ORGANIC FRAMEWORKS; PERFORMANCE; CATALYSTS;
D O I：
10.1016/j.inoche.2018.07.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 2D MOF with unique [Co-5(mu(3)-OH)(2)](8+) subunit, [Co-5(mu(3)-OH)(2)(bcpt)(4)(bib)(2)] (1) (H(2)bcpt = 3,5-bis(3'-carboxyphenyl)-1,2,4-triazole, bib = 1,4-bis(1-imidazoly)benzene) is prepared, which not only shows weak antiferromagnetic interaction between the adjacent Co(II) ion, but also exhibits efficient electrocatalytic hydrogen evolution reaction by the integration with graphene (Gr).
引用
收藏
页码：73 / 77
页数：5
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