A new 2D Co5-cluster based MOF: Crystal structure, magnetic properties and electrocatalytic hydrogen evolution reaction

被引：25

作者：

Tian, Jun-Wu ^{[1
]}

Fu, Meng-Xi ^{[2
]}

Huang, Dan-Dan ^{[1
]}

Wang, Xiao-Kun ^{[1
]}

Wu, Ya-Pan ^{[1
]}

Lu, Jack Y. ^{[3
]}

Li, Dong-Sheng ^{[1
]}

机构：

[1] China Three Gorges Univ, Coll Mat & Chem Engn, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Yichang 443002, Peoples R China

[2] Xian Technol Univ, Sch Mat Sci & Chem Engn, Xian 710072, Shaanxi, Peoples R China

[3] Univ Houstons Clear Lake, Dept Chem, Houston, TX 77058 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 95卷

关键词：

3,5-bis(3 '-carboxyphenyl)-1,2,4-triazole; Co-MOF; Crystal structure; Magnetic properties; Hydrogen evolution reaction; METAL-ORGANIC FRAMEWORKS; PERFORMANCE; CATALYSTS;

D O I：

10.1016/j.inoche.2018.07.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 2D MOF with unique [Co-5(mu(3)-OH)(2)](8+) subunit, [Co-5(mu(3)-OH)(2)(bcpt)(4)(bib)(2)] (1) (H(2)bcpt = 3,5-bis(3'-carboxyphenyl)-1,2,4-triazole, bib = 1,4-bis(1-imidazoly)benzene) is prepared, which not only shows weak antiferromagnetic interaction between the adjacent Co(II) ion, but also exhibits efficient electrocatalytic hydrogen evolution reaction by the integration with graphene (Gr).

引用

页码：73 / 77

页数：5

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