Organic chemistry in ionic liquids using non-thermal energy-transfer processes

被引:43
作者
Habermann, J
Ponzi, S
Ley, SV
机构
[1] IRBM P Angeletti SPA, Merck Sharp & Dohme Res Labs Rome, I-00040 Monte Porzio Catone, Italy
[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
关键词
ionic liquids; microwave; ultrasound; synthesis;
D O I
10.2174/1570193053544454
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
As a result of the chemical industry being under pressure to reduce its usage of volatile solvents ionic liquids are of considerable interest as environmentally benign solvents for organic synthesis programs. Isolation of products is generally facilitated by the fact that ionic liquids form biphasic systems with many organic product mixtures. Recent research has emphasised the use of ionic liquids as solvents and co-solvents in reaction conditions requiring non-thermal heating processes since their ionic nature makes them susceptible to interaction with electromagnetic fields (heating by microwave irradiation). Furthermore, their low vapour pressure allows high temperatures to be reached and leads to interesting behaviour during ultrasound promoted reactions.
引用
收藏
页码:125 / 137
页数:13
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