Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*]

被引：6
作者：
Lau, JPK [1 ]
Wong, WT [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期
关键词：
osmium; rhodium; carbide; X-ray crystallography;
D O I：
10.1016/S1387-7003(03)00095-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The hexanuclear osmium-rhodium carbonyl carbide cluster [OsRh(mu(5)-C)(mu(3)-CO)(CO)(13)Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)(2)](2)[Os5C(CO)(14)] 1 with [Rh-2(Cp*)(2)][BF4](2) 2. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a mu(3)-CO bridging a RhOs2 triangular face. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：733 / 736
页数：4
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