Photocatalysis: a promising route for 21st century organic chemistry

被引:582
作者
Palmisano, Giovanni
Augugliaro, Vincenzo
Pagliaro, Mario
Palmisano, Leonardo
机构
[1] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, Schiavello Grillone Photocatalysis Grp, I-90128 Palermo, Italy
[2] CNR, Ist Mat Nanostrutturati, I-90146 Palermo, Italy
关键词
D O I
10.1039/b700395c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
One of the main goals of 21st century chemistry is to replace environmentally hazardous processes with energy efficient routes allowing to totally avoid the use and production of harmful chemicals and to maximise the quantity of raw material that ends up in the final product. Selective photocatalytic conversions will play a major role in this evolution and this account shows how photocatalysis is offering an alternative green route for the production of organics.
引用
收藏
页码:3425 / 3437
页数:13
相关论文
共 111 条
  • [41] PHOTOCATALYSIS ON TIO2 SURFACES - PRINCIPLES, MECHANISMS, AND SELECTED RESULTS
    LINSEBIGLER, AL
    LU, GQ
    YATES, JT
    [J]. CHEMICAL REVIEWS, 1995, 95 (03) : 735 - 758
  • [42] Photocatalytic reduction of carbon dioxide in the presence of nitrate using TiO2 nanocrystal photocatalyst embedded in SiO2 matrices
    Liu, BJ
    Torimoto, T
    Yoneyama, H
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1998, 115 (03) : 227 - 230
  • [43] Reflection on medium effects on photochemical reactivity
    Liu, RSH
    Hammond, GS
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (05) : 396 - 403
  • [44] Catalytic conversion of methane to more useful chemicals and fuels: a challenge for the 21st century
    Lunsford, JH
    [J]. CATALYSIS TODAY, 2000, 63 (2-4) : 165 - 174
  • [45] Photocatalytic formation of a carbamate through ethanol-assisted carbonylation of p-nitrotoluene
    Maldotti, A
    Amadelli, R
    Samiolo, L
    Molinari, A
    Penoni, A
    Tollari, S
    Cenini, S
    [J]. CHEMICAL COMMUNICATIONS, 2005, (13) : 1749 - 1751
  • [46] Photochemical and photocatalytic reduction of nitrobenzene in the presence of cyclohexene
    Maldotti, A
    Andreotti, L
    Molinari, A
    Tollari, S
    Penoni, A
    Cenini, S
    [J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2000, 133 (1-2) : 129 - 133
  • [47] Photocatalysis with organized systems for the oxofunctionalization of hydrocarbons by O2
    Maldotti, A
    Molinari, A
    Amadelli, R
    [J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3811 - 3836
  • [48] Photocatalytic properties of iron porphyrins revisited in aqueous micellar environment: oxygenation of alkenes and reductive degradation of carbon tetrachloride
    Maldotti, A
    Andreotti, L
    Molinari, A
    Varani, G
    Cerichelli, G
    Chiarini, M
    [J]. GREEN CHEMISTRY, 2001, 3 (01) : 42 - 46
  • [49] Photocatalytic oxidation of aromatic hydrocarbons
    Mao, Y
    Bakac, A
    [J]. INORGANIC CHEMISTRY, 1996, 35 (13) : 3925 - 3930
  • [50] Photocatalytic oxidation of toluene to benzaldehyde by molecular oxygen
    Mao, Y
    Bakac, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (10) : 4219 - 4223