Photocatalysis: a promising route for 21st century organic chemistry

被引：586

作者：

Palmisano, Giovanni

Augugliaro, Vincenzo

Pagliaro, Mario

Palmisano, Leonardo

机构：

[1] Univ Palermo, Dipartimento Ingn Chim Proc & Mat, Schiavello Grillone Photocatalysis Grp, I-90128 Palermo, Italy

[2] CNR, Ist Mat Nanostrutturati, I-90146 Palermo, Italy

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 33期

关键词：

D O I：

10.1039/b700395c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One of the main goals of 21st century chemistry is to replace environmentally hazardous processes with energy efficient routes allowing to totally avoid the use and production of harmful chemicals and to maximise the quantity of raw material that ends up in the final product. Selective photocatalytic conversions will play a major role in this evolution and this account shows how photocatalysis is offering an alternative green route for the production of organics.

引用

页码：3425 / 3437

页数：13

共 111 条

[11] Organic reactions in water:: An efficient zinc-mediated stereoselective synthesis of (E)- and (Z)-trisubstituted alkenes using unactivated alkyl halides [J].

Das, B ;

Banerjee, J ;

Mahender, G ;

Majhi, A .

ORGANIC LETTERS, 2004, 6 (19) :3349-3352

[12] Functional models for rhodium-mediated olefin-oxygenation catalysis [J].

de Bruin, B ;

Budzelaar, PHM ;

Gal, AW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (32) :4142-4157

[13] Photo-catalytic reduction of carbon dioxide to methane using TiO2 as suspension in water [J].

Dey, GR ;

Belapurkar, AD ;

Kishore, K .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 163 (03) :503-508

[14] Polyoxotungstate photoinduced alkylation of electrophilic alkenes by cycloalkanes [J].

Dondi, D ;

Fagnoni, M ;

Molinari, A ;

Maldotti, A ;

Albini, A .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (01) :142-148

[15] Tetrabutylammonium decatungstate-photosensitized alkylation of electrophilic alkenes: Convenient functionalization of aliphatic C-H bonds [J].

Dondi, Daniele ;

Fagnoni, Maurizio ;

Albini, Angelo .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (15) :4153-4163

[16] Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts [J].

Enache, DI ;

Edwards, JK ;

Landon, P ;

Solsona-Espriu, B ;

Carley, AF ;

Herzing, AA ;

Watanabe, M ;

Kiely, CJ ;

Knight, DW ;

Hutchings, GJ .

SCIENCE, 2006, 311 (5759) :362-365

[17] Photocatalytic oxidation of primary and secondary benzylic alcohols to carbonyl compounds catalyzed by H3PW12O40/SiO2 under an O2 atmosphere [J].

Farhadi, S ;

Afshari, M ;

Maleki, M ;

Babazadeh, Z .

TETRAHEDRON LETTERS, 2005, 46 (49) :8483-8486

[18] Photocatalytic reduction of nitro organics over illuminated titanium dioxide:: Role of the TiO2 surface [J].

Ferry, JL ;

Glaze, WH .

LANGMUIR, 1998, 14 (13) :3551-3555

[19] ORGANIC HETEROGENEOUS PHOTOCATALYSIS - CHEMICAL CONVERSIONS SENSITIZED BY IRRADIATED SEMICONDUCTORS [J].

FOX, MA .

ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (09) :314-321

[20]

Fujishima A., 2000, Journal of Photochemistry and Photobiology C: Photochemistry Reviews, V1, P1, DOI [10.1016/S1389-5567(00)00002-2, DOI 10.1016/S1389-5567(00)00002-2]

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