Helical Microporous Nanorods Assembled by Polyoxometalate Clusters for the Photocatalytic Oxidation of Toluene

被引：58

作者：

Yu, Biao ^{[1
]}

Zhang, Simin ^{[1
]}

Wang, Xun ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 32期

基金：

国家重点研发计划; 中国博士后科学基金;

关键词：

microporous materials; nanoparticles; photocatalysis; polyoxometalates; COVALENT ORGANIC FRAMEWORKS; HETEROGENEOUS CATALYSTS; MESOPOROUS SILICA; A(2)B(2) MONOMER; CONSTRUCTION; POLYMERS;

D O I：

10.1002/anie.202105587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Microporous materials are extensively used in catalysis due to their unique pore structures. Among them, microporous materials loaded with polyoxometalates (POMs) exhibit considerable potential for catalysis thanks to the combination of the outstanding redox-catalytic properties of POMs and the characteristics of microporous materials. Based on this, we developed a facile hydrothermal method to synthesize helical microporous nanorods (HMNRs) using POM clusters as building blocks, combining the properties of both POMs and microporous materials while circumventing the complicated loading process. The HMNRs show an enhanced photocatalytic performance for toluene oxidation. Comparatively high activity, superior selectivity towards benzaldehyde, and prominent cycling stability were achieved, manifesting a promising prospect for a future application in photocatalysis.

引用

页码：17404 / 17409

页数：6