Continuous fluorescence excitation-emission matrix monitoring of river organic matter

被引：113

作者：

Carstea, Elfrida M. ^{[1
]}

Baker, Andy ^{[2
]}

Bieroza, Magdalena ^{[3
]}

Reynolds, Darren ^{[4
]}

机构：

[1] Natl Inst R&D Optoelect, RO-077125 Magurele, Romania

[2] Univ New S Wales, Connected Waters Initiat, Water Res Lab, Manly Vale, NSW 2093, Australia

[3] Univ Bristol, Dept Civil Engn, Bristol BS8 1TR, Avon, England

[4] Univ W England, Bristol BS16 1QY, Avon, England

来源：

WATER RESEARCH | 2010年 / 44卷 / 18期

关键词：

Fluorescence spectroscopy; Water quality monitoring; Dissolved organic matter; IN-SITU; SPECTRA; VARIABILITY; TOOL; CALIBRATION; EFFICIENCY; REMOVAL; SYSTEMS; CARBON; WASTE;

D O I：

10.1016/j.watres.2010.06.036

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Real-time fluorescence monitoring has been mostly performed in marine systems, with little progress being made in the application of fluorescence excitation emission matrix (EEM) spectroscopy, especially for freshwater monitoring. This paper presents a two weeks experiment where real-time fluorescence EEM data have been obtained for Bourn Brook, Birmingham, UK, using an in-situ fibre-optic probe. Fluorescence EEMs were measured every 3 min for two weeks, with control 'grab' samples every hour analyzed for fluorescence EEMs as well as pH, conductivity and dissolved organic carbon. Comparison of real-time and control samples showed an excellent agreement, with no evidence of fibre-optic probe fouling. EEMs of different character were identified using self-organizing maps, which demonstrated seven clusters of fluorescence EEMs which related to the intensity of fluorescence and relative intensities of peak T-1 and T-2 vs. peak C and peak A fluorescence. Fluorescence intensity of peaks A and C were observed to increase with rainfall, and a diesel pollution event was detected through an increase in T-2 fluorescence. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：5356 / 5366

页数：11