Synthesis and Structural Study of Dichlorodiazadienes Derived from 4-Methoxybenzaldehyde

被引：2

作者：

Shikhaliyev, N. G. ^{[1
]}

Askerova, U. F. ^{[1
]}

Mukhtarova, S. H. ^{[1
]}

Niyazova, A. A. ^{[1
]}

Magerramov, A. M. ^{[1
]}

Dorovatovskii, P., V ^{[2
]}

Khrustalev, V. N. ^{[3
,4
]}

Nenajdenko, V. G. ^{[5
]}

机构：

[1] Baku State Univ, Baku 1148, Azerbaijan

[2] Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia

[3] Russian Univ Peoples Friendship, Moscow 117198, Russia

[4] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow 119991, Russia

[5] Lomonosov Moscow State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 56卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

catalytic olefination; 1,2-diazabuta-1,3-dienes; hydrazone; CATALYTIC OLEFINATION; EFFICIENT SYNTHESIS; HYDROGEN-BONDS; HALOGEN; DESIGN;

D O I：

10.1134/S1070428020020013

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The transformation of N-substituted N-methoxybenzaldehyde hydrazones into the corresponding 1,2-diazabuta-1.3-dienes under the action of carbon tetrachloride in the presence of copper(I) chloride was studied. It was shown that hydrazones of different nature, containing both donor and acceptor groups in the hydrazine fragment, can be involved in the reaction. Further evidence in favor of a radical mechanism of this transformation was obtained using a 3,5-bis(trifluoromethyl)phenylhydrazine derivative. The structural features of the synthesized products were studied by X-ray diffraction analysis.

引用

收藏

页码：185 / 192

页数：8

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