Activated carbon from wasp hive for aqueous electrolyte supercapacitor application

被引:19
作者
Lobato-Peralta, Diego Ramon [1 ]
Amaro, Rayko [2 ]
Arias, D. M. [1 ]
Cuentas-Gallegos, Ana Karina [1 ,3 ]
Jaramillo-Quintero, Oscar Andres [1 ,4 ]
Sebastian, P. J. [1 ]
Okoye, Patrick U. [1 ]
机构
[1] Inst Energias Renovables IER UNAM, Privada Xochicalco S-N Col Ctr, Temixco 62580, Morelos, Mexico
[2] Inst Politecn Nacl, Lab Nacl Convers & Almacenamiento Energia, CICATA Legaria, Calzada Legaria 694,Col Irrigac, Mexico City 11500, DF, Mexico
[3] Univ Nacl Autonoma Mexico, Ctr Nanociencias & Nanotecnol, Km 107 Carretera Tijuana Ensenada, Ensenada 22800, BC, Mexico
[4] Univ Nacl Autonoma Mexico, CONACYT, Priv Xochicalco S-N Col Ctr, Temixco 62580, Morelos, Mexico
关键词
Energy storage; Electrolyte; Wasp-hive; Activated carbon; Supercapacitors; ONE-STEP SYNTHESIS; ENERGY-STORAGE; POROUS CARBON; PSEUDOCAPACITIVE CONTRIBUTIONS; POTASSIUM CARBONATE; PERFORMANCE; GRAPHENE; ADSORPTION; CHARGE; OXIDE;
D O I
10.1016/j.jelechem.2021.115777
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, a honeycomb-like hierarchical porous activated carbon derived from a sustainable wasp hive was produced by single-step chemical activation with potassium carbonate (K2CO3) as an activating agent at 800 degrees C for 1 h. The activated carbon was tested as a supercapacitor electrode for energy storage. The chemical activation with K2CO3 tailored the topography and surface properties to realize an amorphous macro-meso-microporous activated carbon material with a specific surface area of 765 m2/g and an average pore diameter of 2.4 nm. The highest specific capacitance (225 F/g) in 3-electrode cells was obtained in an acid electrolyte, whereas the neutral and alkaline electrolytes have lower specific capacitance. The wasp hive activated carbon electrode presented specific energy of 5.33 Wh/kg at 0.25 A/g, which exceeds the specific energy of a commercial activated carbon at the same conditions. About 100% coulombic efficiency was achieved with capacitance retention of 83.6% after 5000 charge/discharge cycles.
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页数:10
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