CuS nanostructures prepared by a hydrothermal method

被引：59

作者：

Huang, Qing-Li ^{[1
]}

Chen, Hu ^{[2
]}

Zhang, Yong Cai ^{[2
]}

Wu, Chang Le ^{[1
]}

机构：

[1] Yangzhou Univ, Testing Ctr, Yangzhou City 225009, Jiangsu, Peoples R China

[2] Yangzhou Univ, Key Lab Environm Mat & Environm Engn Jiangsu Prov, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2011年 / 509卷 / 22期

关键词：

Chalcogenides; Crystal growth; Copper sulfide; Microstructure; COPPER(I) THIOUREA COMPLEXES; RAMAN-SPECTRA; PHOTOCATALYTIC PROPERTIES; THIN-FILMS; SULFIDE; FABRICATION; OXIDATION; GROWTH; ROUTE; ART;

D O I：

10.1016/j.jallcom.2011.02.167

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Without using any surfactant or template, novel CuS three-dimensional (3D) structures consisting of nanosheets were successfully synthesized via a convenient one-step hydrothermal approach. X-ray diffraction pattern showed that the as-prepared product was pure hexagonal phase CuS. Scanning electron microscopy and high-resolution transmission electron microscopy images revealed that the as-prepared product comprised 3D microspheres (about 1-3 mu m in diameter), which were further constructed with randomly oriented, single-crystalline CuS nanosheets (about 20nm in thickness). The UV-vis absorption spectrum of the as-synthesized CuS 3D microspheres displayed an optical absorption minimum near 672 nm. Besides, the thermal stability of the as-synthesized CuS 3D microspheres was also studied. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：6382 / 6387

页数：6

共 38 条

[1] Synthesis, vibrational spectra and X-ray structures of copper(I) thiourea complexes
Bombicz, P
Mutikainen, I
Krunks, M
Leskelä, T
Madarász, J
Niinistö, L
[J]. INORGANICA CHIMICA ACTA, 2004, 357 (02) : 513 - 525
[2] Crystal structure of [Cu4(tu)7](SO4)2]•H2O and vibrational spectroscopic studies of some copper(I) thiourea complexes
Bott, RC
Bowmaker, GA
Davis, CA
Hope, GA
Jones, BE
[J]. INORGANIC CHEMISTRY, 1998, 37 (04) : 651 - 657
[3] Catalogue of 45 reference Raman spectra of minerals concerning research in art history or archaeology, especially on corroded metals and coloured glass
Bouchard, M
Smith, DC
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (10) : 2247 - 2266
[4] Fabrication of mesh-like bismuth oxide single crystalline nanoflakes and their visible light photocatalytic activity
Chen, Rui
Shen, Zhu-Rui
Wang, Hu
Zhou, Hui-Jing
Liu, Yu-Ping
Ding, Da-Tong
Chen, Tie-Hong
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (05) : 2588 - 2596
[5] Controlled synthesis of copper sulfide 3D nanoarchitectures through a facile hydrothermal route
Cheng, Zhiguo
Wang, Shaozhen
Si, Dajie
Geng, Baoyou
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 492 (1-2) : L44 - L49
[6] Electrochemical behaviors of CuS as a cathode material for lithium secondary batteries
Chung, JS
Sohn, HJ
[J]. JOURNAL OF POWER SOURCES, 2002, 108 (1-2) : 226 - 231
[7] THE 1ST DIRECT EVIDENCE FOR COPPER(II) CYSTEINE VIBRATIONS IN BLUE COPPER PROTEINS - RESONANCE RAMAN-SPECTRA OF S-34-CYS-LABELED AZURINS REVEAL CORRELATION OF COPPER SULFUR STRETCHING FREQUENCY WITH METAL SITE GEOMETRY
DAVE, BC
GERMANAS, JP
CZERNUSZEWICZ, RS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (25) : 12175 - 12176
[8] Thermal oxidation of covellite (CuS)
Dunn, JG
Muzenda, C
[J]. THERMOCHIMICA ACTA, 2001, 369 (1-2) : 117 - 123
[9] One-step template-free electrosynthesis of 300 μm long copper sulfide nanowires
Ghahremaninezhad, A.
Asselin, E.
Dixon, D. G.
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2011, 13 (01) : 12 - 15
[10] Great influence of a small amount of capping agents on the morphology of SnS particles using xanthate as precursor
Han, Qiaofeng
Wang, Meijuan
Zhu, Junwu
Wu, Xiaodong
Lu, Lude
Wang, Xin
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (05) : 2180 - 2185

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