Mechanisms and consequences of oxygen transfer reactions

被引：1

作者：

Beak, P ^{[1
]}

Anderson, DR ^{[1
]}

Jarboe, SG ^{[1
]}

Kurtzweil, ML ^{[1
]}

Woods, KW ^{[1
]}

机构：

[1] Univ Illinois, Dept Chem, Urbana, IL 61801 USA

来源：

PURE AND APPLIED CHEMISTRY | 2000年 / 72卷 / 12期

关键词：

D O I：

10.1351/pac200072122259

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The geometry about oxygen in the transition-state structures for oxygen transfers from a nitrone to phosphorous, from a percarboxylic acid to a carbon-carbon double bond, and from an N-sulfonyl oxaziridine to a carbon-carbon double bond have been evaluated by the endocyclic restriction test. The former can proceed at an oblique angle, while the latter two require a large angle between the entering and leaving groups on oxygen. This information is used to determine the mechanism of the aldehyde-dependent oxygen transfer from molecular oxygen to a carbon-carbon double bond.

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页码：2259 / 2264

页数：6

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