The swelling characteristics of some hydrogels prepared by ring-opening metathesis polymerization

被引：7

作者：

Hamilton, JG ^{[1
]}

Kay, J ^{[1
]}

Rooney, JJ ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1998年 / 133卷 / 1-2期

关键词：

hydrogel; metathesis polymerization;

D O I：

10.1016/S1381-1169(98)00100-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of hydrogels have been prepared by cross-linking polymers formed by the ring-opening metathesis polymerization of exo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. The polymerization reactions are carried out in various alcoholic solvents which provide ester functionality on the side chain and thereby a means of controlling gel swelling characteristics. These materials swell reversibly in aqueous fluids and their equilibrium water content is sensitive to both the temperature and the pH of the medium. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：83 / 91

页数：9

共 46 条

[41] Cotton fiber modified via N-phenyl anhydride in situ ring-opening polymerization with controllable surface morphology and its wettability [J].

Liu, Kexin ;

Wu, You ;

Xi, Yanni ;

Li, Zhanxiong .

PROGRESS IN ORGANIC COATINGS, 2022, 162

[42] Norbornadiene complexes of molybdenum(II) and their transformation to a catalyst for ring-opening metathesis polymerization:: DFT calculations -: X-ray crystal structure of a new norbornadiene complex [MoCl(GeCl3)(CO)3(η4-nbd)] [J].

Handzlik, Jaroslaw ;

Stosur, Magdalena ;

Kochel, Andrzej ;

Szymanska-Buzar, Teresa .

INORGANICA CHIMICA ACTA, 2008, 361 (02) :502-512

[43] Living Cationic Ring-Opening Polymerization of Hetero Diels-Alder Adducts to Give Multifactor-Controlled and Fast-Photodegradable Vinyl Polymers [J].

Chae, Ju-Hyung ;

Choi, Minyeong ;

Son, Semin ;

Ko, Su-Min ;

Lee, In-Hwan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (31)

[44] Characteristics of zwitterionic sulfobetaine acrylamide polymer and the hydrogels prepared by free-radical polymerization and effects of physical and chemical crosslinks on the UCST [J].

Ning, Jinyan ;

Kubota, Kazuomi ;

Li, Guang ;

Haraguchi, Kazutoshi .

REACTIVE & FUNCTIONAL POLYMERS, 2013, 73 (07) :969-978

[45] Entropically-driven ring-opening polymerization of macrocyclic esters with up to 84-membered rings catalysed by polymer-supported Candida antarctica lipase B [J].

Manzini, Barbara ;

Hodge, Philip ;

Ben-Haida, Abderrazak .

POLYMER CHEMISTRY, 2010, 1 (03) :339-346

[46] The use of polymer-supported Candida antarctica lipase B to achieve the entropically-driven ring-opening polymerization of macrocyclic bile acid derivatives via transesterification: selectivity of the reactions and the structures of the polymers produced [J].

Hodge, Philip ;

Chakiri, Abdel B. .

RSC ADVANCES, 2015, 5 (113) :93057-93066

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