Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal-organic framework Co(4,4′-bipyrazolate)

被引：9

作者：

Taylor, Mercedes K. ^{[1
,2
,3
]}

Juhl, Martin ^{[4
,5
]}

Hadaf, Gul Barg ^{[4
,5
]}

Hwang, Dasol ^{[4
,5
]}

Velasquez, Ever ^{[3
,6
]}

Oktawiec, Julia ^{[2
]}

Lefton, Jonathan B. ^{[7
]}

Runevski, Tomce ^{[7
]}

Long, Jeffrey R. ^{[2
,3
,6
]}

Lee, Ji-Woong ^{[4
,5
]}

机构：

[1] Sandia Natl Labs, Ctr Integrated Nanotechnol, POB 5800, Albuquerque, NM 87185 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[3] Lawrence Berkeley Natl Lab, Mat Sci Div, Berkeley, CA 94720 USA

[4] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark

[5] Univ Copenhagen, Nanosci Ctr, DK-2100 Copenhagen, Denmark

[6] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA

[7] Southern Methodist Univ, Dept Chem, Dallas, TX 75205 USA

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 08期

关键词：

ADSORPTION; METHANE; RAMAN;

D O I：

10.1039/c9cc08614e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile route to 4,4 '-bipyrazole (H(2)bpz) and other symmetric bipyrazoles is achieved via the palladium-catalyzed homocoupling of a pyrazole boronic ester in the presence of air and water, enabling us to provide the first crystal structures and evidence of structural phase changes in the bipyrazolate-based metal-organic framework Co(bpz).

引用

收藏

页码：1195 / 1198

页数：4

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