WO3-TiO2 nanocomposites for paracetamol degradation under visible light
被引:18
作者:
Namshah, Khadijah S.
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机构:
King Khalid Univ, Coll Sci, Main Campus,King Abdullah Rd, Abha, Saudi ArabiaKing Khalid Univ, Coll Sci, Main Campus,King Abdullah Rd, Abha, Saudi Arabia
Namshah, Khadijah S.
[1
]
Mohamed, Reda M.
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机构:
King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
CMRDI, Adv Mat Dept, POB 87, Cairo, EgyptKing Khalid Univ, Coll Sci, Main Campus,King Abdullah Rd, Abha, Saudi Arabia
Mohamed, Reda M.
[2
,3
]
机构:
[1] King Khalid Univ, Coll Sci, Main Campus,King Abdullah Rd, Abha, Saudi Arabia
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
WO3-TiO2;
Visible light;
Paracetamol degradation;
PERSONAL CARE PRODUCTS;
PHOTOCATALYTIC DEGRADATION;
TITANIUM-DIOXIDE;
HUMAN PHARMACEUTICALS;
AQUATIC ENVIRONMENT;
DOPED TIO2;
WATER;
OXIDATION;
REMOVAL;
PHOTODEGRADATION;
D O I:
10.1007/s13204-018-0888-4
中图分类号:
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
TiO2 has wide band gap energy and also it has fast recombination rate for electron and hole. Therefore, titanium dioxide excited by ultraviolet light and its photocatalytic activity is small. Enlargement of titanium dioxide activity can be carried out by separation of electron-hole pairs. In this, TiO2-WO3 nanocomposites with various percent of WO3 were synthesis by sol-gel technique in existence of hexadecyltrimethylammonium bromide as template. Physical, photocatalytic and structural properties of titanium dioxide and TiO2-WO3 nanocomposites were measured by many characterizations tools. Performance of titanium dioxide and TiO2-WO3 nanocomposites were measured for paracetamol degradation using visible light. Titanium dioxide band gap can be tailored by control tungsten trioxide weight percent. 3 wt% of tungsten trioxide reduce band gap to 2.63eV. The optimum weight percent of tungsten trioxide is 3 wt% at which photocatalytic performance for paracetamol degradation is larger than that of TiO2, TiO2-WO(3)1 wt%, TiO2-WO(3)2 wt% and TiO2-WO(3)4 wt% by 33.3, 2.1, 1.6 and 1 times, respectively. TiO2-WO(3)3 wt% has photocatalytic stability for five times.
机构:
Univ Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
Univ Ind Santander, Escuela Quim, Ctr Invest Catalisis CICAT, Piedecuesta, Santander, ColombiaUniv Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
Granados-Oliveros, Gilma
Paez-Mozo, Edgar A.
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Univ Ind Santander, Escuela Quim, Ctr Invest Catalisis CICAT, Piedecuesta, Santander, ColombiaUniv Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
Paez-Mozo, Edgar A.
Martinez Ortega, Fernando
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Univ Ind Santander, Escuela Quim, Ctr Invest Catalisis CICAT, Piedecuesta, Santander, ColombiaUniv Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
Martinez Ortega, Fernando
Ferronato, Corinne
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机构:
Univ Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, FranceUniv Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
Ferronato, Corinne
Chovelon, Jean-Marc
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机构:
Univ Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, FranceUniv Lyon, CNRS, IRCELYON, UMR 5256, F-69622 Villeurbanne, France
机构:
Univ Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South AfricaUniv Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South Africa
Sambaza, Shepherd
Maity, Arjun
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机构:
Univ Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South AfricaUniv Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South Africa
Maity, Arjun
Pillay, Kriveshini
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机构:
Univ Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South AfricaUniv Johannesburg, Dept Chem Sci, POB 17011, ZA-2028 Johannesburg, South Africa