WO3-TiO2 nanocomposites for paracetamol degradation under visible light

被引:18
作者
Namshah, Khadijah S. [1 ]
Mohamed, Reda M. [2 ,3 ]
机构
[1] King Khalid Univ, Coll Sci, Main Campus,King Abdullah Rd, Abha, Saudi Arabia
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
[3] CMRDI, Adv Mat Dept, POB 87, Cairo, Egypt
关键词
WO3-TiO2; Visible light; Paracetamol degradation; PERSONAL CARE PRODUCTS; PHOTOCATALYTIC DEGRADATION; TITANIUM-DIOXIDE; HUMAN PHARMACEUTICALS; AQUATIC ENVIRONMENT; DOPED TIO2; WATER; OXIDATION; REMOVAL; PHOTODEGRADATION;
D O I
10.1007/s13204-018-0888-4
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
TiO2 has wide band gap energy and also it has fast recombination rate for electron and hole. Therefore, titanium dioxide excited by ultraviolet light and its photocatalytic activity is small. Enlargement of titanium dioxide activity can be carried out by separation of electron-hole pairs. In this, TiO2-WO3 nanocomposites with various percent of WO3 were synthesis by sol-gel technique in existence of hexadecyltrimethylammonium bromide as template. Physical, photocatalytic and structural properties of titanium dioxide and TiO2-WO3 nanocomposites were measured by many characterizations tools. Performance of titanium dioxide and TiO2-WO3 nanocomposites were measured for paracetamol degradation using visible light. Titanium dioxide band gap can be tailored by control tungsten trioxide weight percent. 3 wt% of tungsten trioxide reduce band gap to 2.63eV. The optimum weight percent of tungsten trioxide is 3 wt% at which photocatalytic performance for paracetamol degradation is larger than that of TiO2, TiO2-WO(3)1 wt%, TiO2-WO(3)2 wt% and TiO2-WO(3)4 wt% by 33.3, 2.1, 1.6 and 1 times, respectively. TiO2-WO(3)3 wt% has photocatalytic stability for five times.
引用
收藏
页码:2021 / 2030
页数:10
相关论文
共 50 条
  • [21] Photocatalytic performance of hybrid WO3/TiO2 nanomaterials for the degradation of methylene blue under visible light irradiation
    Tahir, Muhammad Bilal
    Farman, Sohail
    Rafique, Muhammad
    Shakil, Muhammad
    Khan, Muhammad Isa
    Ijaz, Mohsin
    Mubeen, Iqra
    Ashraf, Maria
    Riaz, Khalid Nadeem
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2021, 101 (10) : 1448 - 1460
  • [22] Synthesize of heterostructure TiO2 by simultaneous doping of double silver and phosphate to degradation of methylene blue under visible light
    Moeini, Zohre
    Hoseini, Mohammad
    Dehghani, Mansooreh
    Samaei, Mohammadreza
    Jafari, Saeed
    Taghavi, Mahmoud
    Azhdarpoor, Abooalfazl
    APPLIED WATER SCIENCE, 2024, 14 (03)
  • [23] Enhanced photosensitized degradation of rhodamine B on CdS/TiO2 nanocomposites under visible light irradiation
    Li, Wenjuan
    Cui, Xiaoli
    Wang, Peixian
    Shao, Yu
    Li, Danzhen
    Teng, Fei
    MATERIALS RESEARCH BULLETIN, 2013, 48 (09) : 3025 - 3031
  • [24] One-step synthesis of TiO2/γ-Fe2O3/GO nanocomposites for visible light-driven degradation of ciprofloxacin
    Wang, Feifei
    Yu, Xiaolin
    Ge, Maofa
    Wu, Sujun
    CHEMICAL ENGINEERING JOURNAL, 2020, 384
  • [25] Ultrasonically assisted hydrothermal synthesis of tungsten(VI) oxide-TiO2 nanocomposites for enhanced photocatalytic degradation of non-narcotic drug paracetamol under natural solar light: insights into degradation pathway, mechanism, and toxicity assessment
    Shah, Aarif Hussain
    Rather, Mushtaq Ahmad
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2023, 30 (41) : 93916 - 93933
  • [26] Photocatalytic degradation of contaminants of concern with composite NF-TiO2 films under visible and solar light
    Barndok, H.
    Pelaez, M.
    Han, C.
    Platten, W. E., III
    Campo, P.
    Hermosilla, D.
    Blanco, A.
    Dionysiou, D. D.
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2013, 20 (06) : 3582 - 3591
  • [27] Fabrication of MnCo2O4@WO3 heterostructured nanocomposites with enhanced photocatalytic reduction of Cr(VI) ions under visible light irradiation
    Basaleh, Amal S.
    El-Hout, Soliman I.
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2023, 168
  • [28] Effective degradation of tetracycline by mesoporous Bi2WO6 under visible light irradiation
    Chu, Xiaolong
    Shan, Guoqiang
    Chang, Chun
    Fu, Yu
    Yue, Longfei
    Zhu, Lingyan
    FRONTIERS OF ENVIRONMENTAL SCIENCE & ENGINEERING, 2016, 10 (02) : 211 - 218
  • [29] Fabrication of Bi2O3/TiO2 nanocomposites and their applications to the degradation of pollutants in air and water under visible-light
    Chakraborty, Ashok Kumar
    Hossain, Md Emran
    Rhaman, Md Masudur
    Sobahan, K. M. A.
    JOURNAL OF ENVIRONMENTAL SCIENCES, 2014, 26 (02) : 458 - 465
  • [30] Synthesis and characterization of novel unsymmetrical phthalocyanine/TiO2 composites and their evaluation as photocatalysts for degradation of 4-chlorophenol under visible light
    Sutculer, Yunus Alp
    Gezek, Gorkem
    Mahmiani, Yaghub
    Sevim, Altug Mert
    TURKISH JOURNAL OF CHEMISTRY, 2018, 42 (03) : 704 - 718