D1→D0 and D2→D0 transitions of the jet-cooled p-chlorobenzyl radical

被引：46

作者：

Lee, SK ^{[1
]}

Baek, DY

机构：

[1] Pusan Natl Univ, Dept Chem, Pusan 609735, South Korea

[2] Pusan Natl Univ, Chem Inst Funct Mat, Pusan 609735, South Korea

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 304卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(99)00294-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The jet cooled p-chlorobenzyl radical has been generated with a He carrier gas from p-chlorotoluene in a corona excited supersonic expansion. The vibronic emission spectrum in the transitions of D-1(1(2)A(2)) --> D-0(1(2)B(2)) and D-2(2(2)B(2)) --> D-0(1(2)B(2)) of the p-chlorobenzyl radical has been recorded with a long-path monochromator. The spectrum exhibits well-resolved vibronic structure from which the vibrational frequencies in the ground electronic state have been accurately determined. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：39 / 44

页数：6

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