Applications of microwave in organic synthesis: An improved one-step synthesis of metallophthalocyanines and a new modified microwave oven for dry reactions

被引：45
作者：
Villemin, D
Hammadi, M
Hachemi, M
Bar, N
机构：
[1] Univ Caen, UMR CNRS 6507, ISMRA, Ecole Natl Super Ingenieurs Caen, F-14050 Caen, France
[2] Univ Boumerdes, Fac Sci Ingenieur, Boumerdes 35000, Algeria
来源：
MOLECULES | 2001年 / 6卷 / 10期
关键词：
phthalocyanine; microwave; complexes;
D O I：
10.3390/61000831
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Metallophthalocyanine complexes are obtained quickly and efficiently by the reaction of phthalodinitrile with hydrated metallic salts without solvent and under microwave irradiation. The use of a modified commercial microwave oven to perform this type of reactions under dry conditions is described, Metallophthalocyanines and metallododecachlorophthalocyanines of some divalent metals can be also obtained from phthalic or tetrachlorophthalic anhydrides with hydrated metallic salt and urea under microwave irradiation and without solvent.
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页码：831 / 844
页数：14
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