Hydrogen-Bonded Dihydrotetraazapentacenes

被引:60
作者
He, Zikai [1 ]
Liu, Danqing [1 ]
Mao, Renxin [1 ]
Tang, Qin [1 ]
Miao, Qian [1 ]
机构
[1] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China
关键词
THIN-FILM TRANSISTORS; NITROGEN; HETEROPENTACENES; MOBILITIES; ACENES;
D O I
10.1021/ol203404q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three new members of N-heteropentacenes explored herein have adjacent pyrazine and dihydropyrazine rings at one end of the pentacene backbone. Interesting findings from this study include self-complementary N-H center dot center dot center dot N-H-bonds in the solid state, solvent-dependent UV-vis absorption caused by H-bonding, and new p-type organic semiconductors with field effect mobility up to 0.7 cm(2) V-1 s(-1).
引用
收藏
页码:1050 / 1053
页数:4
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