BIOMIMETIC CHEMISTRY Merging the old with the new

被引:22
|
作者
Darensbourg, Marcetta Y. [1 ]
Bethel, Ryan D. [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
ACTIVE-SITE; HYDROGENASES; MODELS; RELEVANT; CLUSTER;
D O I
10.1038/nchem.1228
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The classic organometallic compound ferrocene has been combined with a unique diiron unit in the latest synthetic analogue of an enzyme active site, achieving the three functionalities needed for a working model of diiron hydrogenase, itself of ancient origin.
引用
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页码:11 / 13
页数:4
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