In-plane 2-D patterning of microporous layer by inkjet printing for water management of polymer electrolyte fuel cell

被引:24
作者
Bae, Insung [1 ,2 ]
Kim, Bongsoo [1 ]
Kim, Young [1 ]
Kim, Hyuk [1 ]
Oh, Keun-Hwan [1 ]
机构
[1] LG Chem Ltd, Corp R&D, Future Technol Ctr, 188 Munji Ro, Daejeon 305380, South Korea
[2] Hannam Univ, Dept Adv Mat & Chem Engn, 1646 Yuseong Daero, Daejeon 34054, South Korea
基金
新加坡国家研究基金会;
关键词
Microporous layer; Polymer electrolyte membrane fuel cell; Water management; GeoDict; Inkjet printing; GAS-DIFFUSION LAYERS; MEMBRANE; DEGRADATION; PERFORMANCE; DURABILITY; RESISTANCE;
D O I
10.1016/j.renene.2019.07.003
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
An appropriate water balance between the conservation of the membrane humidity and the reduction of excess water in the cell remains a key challenge for commercialization of polymer electrolyte fuel cells (PEFCs). Here, we report a microporous layer (MPL) consisting of line patterns with different morphologies by using inkjet printing method, which provides a better water transport pathway not limiting by mass transport for reactant gases to reach the catalyst layer. The pattern-MPL coated on the gas diffusion backing layer (P-GDL) increases the power performance at 50 and 32% RH conditions comparing to commercial one (SGL, 39BC). This result suggests that the in-plane different porous pattern of MPL possesses the significant potential to improve the PEFCs performance with the water balance in the membrane/electrode assembly (MEA). (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:960 / 967
页数:8
相关论文
共 38 条
[1]   Characterizing the hydraulic properties of paper coating layer using FIB-SEM tomography and 3D pore-scale modeling [J].
Aslannejad, H. ;
Hassanizadeh, S. M. ;
Raoof, A. ;
de Winter, D. A. M. ;
Tomozeiu, N. ;
van Genuchten, M. Th. .
CHEMICAL ENGINEERING SCIENCE, 2017, 160 :275-280
[2]   Nanostructured composite membrane with cross-linked sulfonated poly (arylene ether ketone)/silica for high-performance polymer electrolyte membrane fuel cells under low relative humidity [J].
Bae, Insung ;
Oh, Keun-Hwan ;
Yun, Minhyuk ;
Kang, Min Kwan ;
Song, Hyun Hoon ;
Kim, Hyuk .
JOURNAL OF MEMBRANE SCIENCE, 2018, 549 :567-574
[3]   Asymmetric silica composite polymer electrolyte membrane for water management of fuel cells [J].
Bae, Insung ;
Oh, Keun-Hwan ;
Yun, Sung-Hyun ;
Kim, Hyuk .
JOURNAL OF MEMBRANE SCIENCE, 2017, 542 :52-59
[4]   Measurement of Oxygen Transport Resistance in PEM Fuel Cells by Limiting Current Methods [J].
Baker, Daniel R. ;
Caulk, David A. ;
Neyerlin, Kenneth C. ;
Murphy, Michael W. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (09) :B991-B1003
[5]   A multi-scale approach to material modeling of fuel cell diffusion media [J].
Becker, Juergen ;
Wieser, Christian ;
Fell, Stephan ;
Steiner, Konrad .
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 2011, 54 (7-8) :1360-1368
[6]   Cerium Oxide Decorated Polymer Nanofibers as Effective Membrane Reinforcement for Durable, High-Performance Fuel Cells [J].
Breitwieser, Matthias ;
Klose, Carolin ;
Hartmann, Armin ;
Buechler, Andreas ;
Klingele, Matthias ;
Vierrath, Severin ;
Zengerle, Roland ;
Thiele, Simon .
ADVANCED ENERGY MATERIALS, 2017, 7 (06)
[7]   Simple fabrication of 12 μm thin nanocomposite fuel cell membranes by direct electrospinning and printing [J].
Breitwieser, Matthias ;
Klose, Carolin ;
Klingele, Matthias ;
Hartmann, Armin ;
Erben, Johannes ;
Cho, Hyeongrae ;
Kerres, Jochen ;
Zengerle, Roland ;
Thiele, Simon .
JOURNAL OF POWER SOURCES, 2017, 337 :137-144
[8]   The Control and Effect of Pore Size Distribution in AEMFC Catalyst Layers [J].
Britton, Benjamin ;
Holdcroft, Steven .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (05) :F353-F358
[9]   Novel gas diffusion layer with water management function for PEMFC [J].
Chen, J ;
Matsuura, T ;
Hori, M .
JOURNAL OF POWER SOURCES, 2004, 131 (1-2) :155-161
[10]   Gas diffusion layer for proton exchange membrane fuel cells-A review [J].
Cindrella, L. ;
Kannan, A. M. ;
Lin, J. F. ;
Saminathan, K. ;
Ho, Y. ;
Lin, C. W. ;
Wertz, J. .
JOURNAL OF POWER SOURCES, 2009, 194 (01) :146-160