Fabrication of magnetic carbon nanotubes using a metal-impregnated polymer precursor

被引:128
作者
Jang, JS
Yoon, HS
机构
[1] Seoul Natl Univ, Hyperstructured Organ Mat Res, Seoul 151742, South Korea
[2] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
关键词
D O I
10.1002/adma.200305296
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
gamma-Fe2O3-impregnated magnetic carbon nanotubes (CNTs) have been fabricated by the carbonization of polypyrrole (PPy) nanotubes. It is found that PPy nanotubes form graphitic structures at a low temperature (800degreesC). Magnetic CNTs (see Figure) show ferromagnetic behavior even at 300 K and the main magnetic phase of the CNTs is gamma-Fe2O3. This novel fabrication approach is expected to provide an alternative way to fabricate CNTs.
引用
收藏
页码:2088 / +
页数:5
相关论文
共 43 条
  • [1] NATURE OF IMPURITIES IN PI-CONJUGATED POLYMERS PREPARED BY FERRIC-CHLORIDE AND THEIR EFFECT ON THE ELECTRICAL-PROPERTIES OF METAL-INSULATOR-SEMICONDUCTOR STRUCTURES
    ABDOU, MSA
    LU, XT
    XIE, ZW
    ORFINO, F
    DEEN, MJ
    HOLDCROFT, S
    [J]. CHEMISTRY OF MATERIALS, 1995, 7 (04) : 631 - 641
  • [2] CAPILLARITY-INDUCED FILLING OF CARBON NANOTUBES
    AJAYAN, PM
    IIJIMA, S
    [J]. NATURE, 1993, 361 (6410) : 333 - 334
  • [3] Effects of temperature on the conductivity of AOT/isooctane/water microemulsions.: Influence of salts
    Alvarez, E
    García-Río, L
    Mejuto, JC
    Navaza, JM
    Pérez-Juste, J
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (04) : 850 - 853
  • [4] Electric conductivity changes of polypyrrole and polythiophene films with heat-treatment
    Ando, E
    Onodera, S
    Iino, M
    Ito, O
    [J]. CARBON, 2001, 39 (01) : 101 - 108
  • [5] Bao JC, 2002, ADV MATER, V14, P1483, DOI 10.1002/1521-4095(20021016)14:20<1483::AID-ADMA1483>3.0.CO
  • [6] 2-6
  • [7] Carbon nanotubule membranes for electrochemical energy storage and production
    Che, GL
    Lakshmi, BB
    Fisher, ER
    Martin, CR
    [J]. NATURE, 1998, 393 (6683) : 346 - 349
  • [8] deFaria DLA, 1997, J RAMAN SPECTROSC, V28, P873, DOI 10.1002/(SICI)1097-4555(199711)28:11<873::AID-JRS177>3.0.CO
  • [9] 2-B
  • [10] LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES
    EBBESEN, TW
    AJAYAN, PM
    [J]. NATURE, 1992, 358 (6383) : 220 - 222