Separation of Pb and Bi from proton irradiated lead-bismuth eutectic target using different anion exchangers

被引:8
|
作者
Choudhury, Dibyasree [1 ]
Lahiri, Susanta [1 ,2 ]
机构
[1] Saha Inst Nucl Phys, 1-AF Bidhannagar, Kolkata 700064, India
[2] Homi Bhabha Natl Inst, Kolkata, India
关键词
Lead-bismuth eutectic; Liquid liquid extraction; Solid liquid extraction; TOA; Aliquat; 336; Dowex; 1; ELEMENTS; HAFNIUM;
D O I
10.1007/s10967-018-6125-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Lead-bismuth eutectic (LBE) is the proposed material for use as converter targets in the ISOL facilities globally. In this paper, an LBE target was irradiated with 22MeV proton beam for 7.6h to produce Bi-203,Bi-204,Bi-205,Bi-206, Pb-203 along with Po-207. Separation of bulk Pb and Bi has been carried out using Aliquat-336 (tricaprylmethylammonium chloride), TOA (trioctyl amine) and DOWEX-1 as extractants. Bi was selectively extracted to the organic/solid phase leaving Pb in aqueous medium. High separation factor between Pb and Bi was observed when 0.5M TOA and 1M HNO3 were used as organic and aqueous phase respectively.
引用
收藏
页码:1967 / 1972
页数:6
相关论文
共 34 条
  • [21] SECONDARY PARTICLES PRODUCED BY 1.5 GEV PROTON BEAMS INCIDENT ON LEAD-BISMUTH EUTECTIC TARGET OF C-ADS
    Wu, Hongli
    Wang, Xiangqi
    Tang, Jingyu
    Bi, Yuanjie
    Li, Weimin
    Shang, Lei
    PROCEEDINGS OF THE 20TH INTERNATIONAL CONFERENCE ON NUCLEAR ENGINEERING AND THE ASME 2012 POWER CONFERENCE - 2012, VOL 1, 2012, : 807 - 811
  • [22] Estimation of polonium radionuclides in proton irradiated lead-bismuth eutectic (LBE) targets by LSC-TDCR technique and gamma spectrometry
    Choudhury, Dibyasree
    Lahiri, Susanta
    EUROPEAN PHYSICAL JOURNAL A, 2018, 54 (12):
  • [23] Estimation of polonium radionuclides in proton irradiated lead-bismuth eutectic (LBE) targets by LSC-TDCR technique and gamma spectrometry
    Dibyasree Choudhury
    Susanta Lahiri
    The European Physical Journal A, 2018, 54
  • [24] Unfolding of polonium distribution in depth of irradiated lead-bismuth eutectic from α-particle pulse-height distribution
    Miura, T
    Obara, T
    Sekimoto, H
    APPLIED RADIATION AND ISOTOPES, 2004, 61 (06) : 1307 - 1311
  • [25] Investigations on the release of mercury from liquid eutectic lead-bismuth alloy under different gas atmospheres
    Neuhausen, J
    NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2006, 562 (02): : 702 - 705
  • [26] Preliminary measurements from a thick lead-bismuth target using 800 MeV protons
    James, MR
    Klann, RT
    Morgan, GL
    Pitcher, EJ
    Paciotti, MA
    Oostens, JM
    UTILISATION AND RELIABILITY OF HIGH POWER PROTON ACCELERATORS, WORKSHOP PROCEEDINGS, 2003, : 193 - 200
  • [27] The effect of impurities Pb, Bi, and PbO on erosion properties of Lead-Bismuth Eutectic alloy on Fe3O4 oxide film by first principle calculations
    Zhang, Sun Jing Kang
    Cai, Jun
    Yang, Fu An
    SURFACE AND INTERFACE ANALYSIS, 2022, 54 (07) : 786 - 793
  • [28] Electrolytic separation of Dy from Sm in molten LiCl-KCl using Pb-Bi eutectic alloy cathode
    Li, Zhuyao
    Tang, Dandan
    Meng, Siyu
    Gu, Longhao
    Dai, Ying
    Liu, Zhirong
    SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 276
  • [29] Separation of no-carrier-added 203Pb, a surrogate radioisotope, from proton irradiated natTl2CO3 target using calcium alginate hydrogel beads
    Sarkar, Kangkana
    Lahiri, Susanta
    Sen, Kamalika
    RADIOCHIMICA ACTA, 2016, 104 (12) : 891 - 896
  • [30] SEPARATION OF BI-206 FROM CYCLOTRON BOMBARDED LEAD TARGETS USING ANION-EXCHANGE CHROMATOGRAPHY IN NITRIC-HYDROBROMIC ACID MIXTURES
    VANDERWALT, TN
    STRELOW, FWE
    HAASBROEK, FJ
    INTERNATIONAL JOURNAL OF APPLIED RADIATION AND ISOTOPES, 1982, 33 (04): : 301 - 303