Self-Assembly of Amphiphilic Block Copolymers during Reversible Addition-Fragmentation Chain Transfer Heterophase Polymerization: Problems, Achievements, and Outlook

被引：7

作者：

Chernikova, E. V. ^{[1
]}

Lysenko, E. A. ^{[1
]}

Serkhacheva, N. S. ^{[2
]}

Prokopov, N. I. ^{[2
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia

[2] MIREA Russian Technol Univ, Lomonosov Inst Fine Chem Technol, Moscow 119571, Russia

来源：

POLYMER SCIENCE SERIES C | 2018年 / 60卷

基金：

俄罗斯科学基金会;

关键词：

RAFT DISPERSION POLYMERIZATION; CONTROLLED/LIVING RADICAL POLYMERIZATION; INITIO EMULSION POLYMERIZATION; NANOPARTICLE-TO-VESICLE; ONE-POT SYNTHESIS; N-BUTYL ACRYLATE; IN-SITU; DIBLOCK COPOLYMER; NANO-OBJECTS; MEDIATED POLYMERIZATION;

D O I：

10.1134/S1811238218020042

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The formation of dispersions of amphiphilic block copolymer particles with the controlled morphology via heterophase polymerization mediated by reversible addition-fragmentation agents is considered. Variants of dispersion, emulsion, and seeded polymerizations are analyzed, and the mechanism of this process is discussed. Special attention is focused on issues related to control over the morphology of the formed particles immediately during synthesis and methods of its transformation in the resulting dispersions.

引用

页码：192 / 218

页数：27

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