Polyaniline as Photocatalytic Promoter in Black Anatase TiO2

被引:16
作者
Kavil, Jithesh [1 ]
Ullattil, Sanjay Gopal [2 ]
Alshahrie, Ahmed [3 ]
Periyat, Pradeepan [1 ]
机构
[1] Univ Calicut, Dept Chem, Calicut 673635, Kerala, India
[2] Univ Calicut, Dept Nanosci & Technol, Calicut 673635, Kerala, India
[3] King Abdulaziz Univ, Ctr Nanotechnol, Jeddah 21589, Saudi Arabia
关键词
Photocatalyst; Heterojunction; PANI; Black TiO2; LIGHT; NANOPARTICLES; PERFORMANCE; ABSORPTION; DEGRADATION; FABRICATION; POLYMER;
D O I
10.1016/j.solener.2017.10.049
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The effect of conducting polymer matrix, polyaniline (PANI) on the photocorrosion and photochemical activities of Black Anatase Titania (BAT) has been systematically investigated. PANI-BAT composite has been fabricated by a modified hydrothermal method and successive in situ polymerization of aniline. This hybrid material has shown excellent photo catalytic activity than BAT under visible light. The rate constant value of dye degradation in presence of the PANI-BAT composite was found 2.4 x 10(-2) min(-1), which is 1.5 times. greater than that of the commercially available photocatalyst Degussa P25 and BAT. The study unveils the strong correlation between electrochemical impedance measurements and the photochemical results.
引用
收藏
页码:792 / 796
页数:5
相关论文
共 36 条
[1]   N-DOPED AND P-DOPED POLYDITHIENO[3,4-B-3',4'-D] THIOPHENE - A NARROW-BAND GAP POLYMER FOR REDOX SUPERCAPACITORS [J].
ARBIZZANI, C ;
CATELLANI, M ;
MASTRAGOSTINO, M ;
MINGAZZINI, C .
ELECTROCHIMICA ACTA, 1995, 40 (12) :1871-1876
[2]   Visible-light photocatalysis in nitrogen-doped titanium oxides [J].
Asahi, R ;
Morikawa, T ;
Ohwaki, T ;
Aoki, K ;
Taga, Y .
SCIENCE, 2001, 293 (5528) :269-271
[3]   Photocatalytic activity of CU2O/TiO2, Bi2O3/TiO2 and ZnMn2O4/TiO2 heterojunctions [J].
Bessekhouad, Y ;
Robert, D ;
Weber, JV .
CATALYSIS TODAY, 2005, 101 (3-4) :315-321
[4]   Fabrication of TiO2@PANI nanobelts with the enhanced absorption and photocatalytic performance under visible light [J].
Chen, Xi ;
Li, Huankun ;
Wu, Hanshuo ;
Wu, Yuxin ;
Shang, Yanyang ;
Pan, Jun ;
Xiong, Xiang .
MATERIALS LETTERS, 2016, 172 :52-55
[5]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[6]   Black titanium dioxide (TiO2) nanomaterials [J].
Chen, Xiaobo ;
Liu, Lei ;
Huang, Fuqiang .
CHEMICAL SOCIETY REVIEWS, 2015, 44 (07) :1861-1885
[7]   Increasing Solar Absorption for Photocatalysis with Black Hydrogenated Titanium Dioxide Nanocrystals [J].
Chen, Xiaobo ;
Liu, Lei ;
Yu, Peter Y. ;
Mao, Samuel S. .
SCIENCE, 2011, 331 (6018) :746-750
[8]  
Ghosh S, 2015, NAT MATER, V14, P505, DOI [10.1038/NMAT4220, 10.1038/nmat4220]
[9]   Microscale Hierarchical Three-Dimensional Flowerlike TiO2/PANI Composite: Synthesis, Characterization, and Its Remarkable Photocatalytic Activity on Organic Dyes under UV-Light and Sunlight Irradiation [J].
Guo, Na ;
Liang, Yimai ;
Lan, Shi ;
Liu, Lu ;
Zhang, Junjun ;
Ji, Guijuan ;
Gan, Shucai .
JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (32) :18343-18355
[10]   Dramatic visible photocatalytic degradation performances due to synergetic effect of TiO2 with PANI [J].
Hao Zhang ;
Ruilong Zong ;
Jincai Zhao ;
Yongfa Zhu .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2008, 42 (10) :3803-3807