The first chelating olefin:: Solid-state structure of bis-(η1-4-phenyl-η2-1-butene)silver (I) tetrafluoroborate

被引：7

作者：

Whitcomb, D. R. ^{[1
]}

Rajeswaran, M. ^{[2
]}

机构：

[1] Carestrean Hlth, Oakdale, MN 55128 USA

[2] Eastman Kodak Co, Rochester, NY 14650 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 24期

关键词：

silver; olefin; 4-phenyl-1-butene; chelate; silver-carbon bond; structure;

D O I：

10.1016/j.jorganchem.2007.08.036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A complex of 4-phenyl-1-butene with silver ion has been prepared by mixing silver (I) tetrafluoroborate with the neat ligand at room temperature. Purification by crystallization produces a stable complex characterized by solid-state structure. The bis-(eta(1)-4-phenyl-eta(2)-1-butene) silver(I) tetrafluoroborate complex contains a pair of olefin ligands that chelate a single silver atom via both olefin and aromatic Ag-C bonds. This is the first chelated organometallic silver complex reported in the literature assembled with only Ag-C bonds. (C) 2007 Elsevier B.V. All rights reserved.

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页码：5513 / 5516

页数：4

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