Regio- and diasteroselectivity of rhodium-catalyzed ring opening reaction of oxabenzonorbornadienes with heteroatom nucleophiles

被引：0

作者：

Yang, DQ ^{[1
]}

Zeng, HP ^{[1
]}

机构：

[1] S China Normal Univ, Dept Chem, Guangzhou 510631, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2003年 / 14卷 / 07期

关键词：

ring opening; rhodium-catalyzed; oxabenzonorbornadienes; heteroatom nucleophiles;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new rhodium catalyzed ring opening reaction of oxabenzonorbomadienes and its derivatives was described. This reaction forms a new carbon-nitrogen bond via an intermolecular allylic displacement of the bridgehead oxygen with a piperazine's derivatives, which proceeds with very high regioselectivity.

引用

页码：697 / 699

页数：3

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