Incorporation of iron nanoparticles into clinoptilolite and its application for the removal of cationic and anionic dyes

被引：31
作者：
Nairat, Muath [1 ]
Shahwan, Talal [1 ]
Eroglu, Ahmet E. [2 ]
Fuchs, Harald [3 ,4 ]
机构：
[1] Birzeit Univ, Dept Chem, Birzeit, West Bank, Israel
[2] Izmir Inst Technol, Dept Chem, TR-35430 Izmir, Turkey
[3] Univ Munich, Inst Phys, D-81377 Munich, Germany
[4] Univ Munich, Ctr Nanotechnol CeNTech, D-81377 Munich, Germany
来源：
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2015年 / 21卷
关键词：
Clinoptilolite; Iron nanoparticles; Methyl orange; Methylene blue; ZERO-VALENT IRON; AQUEOUS-SOLUTION; ADSORPTION; TCE; DECHLORINATION; DEGRADATION; REDUCTION; PARTICLES; MECHANISM; GREEN;
D O I：
10.1016/j.jiec.2014.05.027
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study reports the preparation of composite sorbents of iron nanoparticles (nZVI) and clinoptilolite at various iron/clinoptilolite ratios. The composites were characterized using various characterization techniques. The material was used for the removal of methylene blue (MB) and methyl orange (MO) as model cationic and anionic dyes. The experiments investigated the effects of time, loading, initial pH, reusability, and temperature on the removal process. According to the results, Cl-nZVI showed fast and quantitative removal over a wide range of concentrations. The removal process was endothermic in nature, and the composite demonstrated reusability for several trials. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1143 / 1151
页数：9
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