Toward quasi-solid state Dye-sensitized Solar Cells: Effect of γ-Al2O3 nanoparticle dispersion into liquid electrolyte

被引:23
|
作者
Sacco, Adriano [1 ]
Lamberti, Andrea [1 ,2 ]
Gerosa, Matteo [1 ,2 ]
Bisio, Chiara [3 ,4 ]
Gatti, Giorgio [3 ]
Carniato, Fabio [3 ]
Shahzad, Nadia [1 ,2 ]
Chiodoni, Angelica [1 ]
Tresso, Elena [1 ,2 ]
Marchese, Leonardo [3 ]
机构
[1] Ist Italiano Tecnol, Ctr Space Human Robot Polito, I-10129 Turin, Italy
[2] Politecn Torino, Appl Sci & Technol Dept, I-10129 Turin, Italy
[3] Univ Piemonte Orientale, Dipartimento Sci & Innovaz Tecnol, I-15121 Alessandria, Italy
[4] ISTM CNR Ist Sci & Tecnol Mol, I-20133 Milan, Italy
关键词
Dye-sensitized Solar Cell; gamma-Al2O3; nanoparticles; Quasi-solid state electrolyte; Stability; IMPEDANCE SPECTROSCOPY; EFFICIENCY; KINETICS; POLYMER; CLAY;
D O I
10.1016/j.solener.2014.10.034
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, we report on the effect of gamma-Al2O3 nanoparticle (NP) addition into liquid electrolyte for Dye-sensitized Solar Cell (DSC) application. gamma-Al2O3 was prepared by a fast ultrasound-assisted sol gel procedure allowing the formation of gamma-Al2O3 crystals with nanometric size and high specific surface area. A quasi-solid state electrolyte was prepared by dispersing 5 wt% of gamma-Al2O3 NPs in commercially available electrolytic solution, and optical and electrical properties were analyzed and compared to the bare liquid electrolyte. DSCs were fabricated exploiting NP-based electrolyte and fully characterized. In comparison with liquid electrolyte-based cells, the quasi-solid ones exhibit the same photovoltaic performances and a noticeable extended stability over the time. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:125 / 134
页数:10
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