Parallel synthesis of terminal alkynes using a ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate

被引：46

作者：

Barrett, AGM ^{[1
]}

Hopkins, BT ^{[1
]}

Love, AC ^{[1
]}

Tedeschi, L ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 05期

关键词：

D O I：

10.1021/ol049915z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

ROMPgel-supported ethyl 1-diazo-2-oxopropylphosphonate has been prepared, and the supported reagent has been effectively employed in the conversion of a variety of aldehydes into terminal alkynes under mild reaction conditions. The influence of cross-link structure, comonomers, and polymer structure on reaction efficiency has been examined.

引用

页码：835 / 837

页数：3

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