Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols.: The unexpected oxidation of primary alcohols to carboxylic ligands

被引：1

作者：

Soler, J ^{[1
]}

Moldes, I ^{[1
]}

de la Encarnación, E ^{[1
]}

Ros, J ^{[1
]}

机构：

[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 01期

关键词：

ruthenium; carboxylate; formate; alkoxide;

D O I：

10.1016/S0022-328X(98)01131-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dinuclear ruthenium (I) complexes [Ru-2(HCO2)(2)(CO)(4)(PPh3)(2)] react with primary alcohols R'CH2OH in refluxing toluene, giving rise to [Ru-2(R'CO2)(2)(CO)(4)(PPh3)(2)] compounds. Other carboxylate bridging complexes react with alcohols R " OH to give very unstable alkoxide compounds [Ru-2(R " O)(2)(CO)(4)(PPh3)(2)]. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：108 / 109

页数：2