Reactions of dinuclear carboxylate ruthenium (I) complexes with alcohols.: The unexpected oxidation of primary alcohols to carboxylic ligands

被引：1
|
作者：
Soler, J [1 ]
Moldes, I [1 ]
de la Encarnación, E [1 ]
Ros, J [1 ]
机构：
[1] Univ Autonoma Barcelona, Dept Quim, E-08193 Barcelona, Spain
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 01期
关键词：
ruthenium; carboxylate; formate; alkoxide;
D O I：
10.1016/S0022-328X(98)01131-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dinuclear ruthenium (I) complexes [Ru-2(HCO2)(2)(CO)(4)(PPh3)(2)] react with primary alcohols R'CH2OH in refluxing toluene, giving rise to [Ru-2(R'CO2)(2)(CO)(4)(PPh3)(2)] compounds. Other carboxylate bridging complexes react with alcohols R " OH to give very unstable alkoxide compounds [Ru-2(R " O)(2)(CO)(4)(PPh3)(2)]. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：108 / 109
页数：2
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