FeS@tubular mesoporous carbon as high capacity and long cycle life anode materials for lithium- and sodium-ions batteries

An ordered tubular FeS@tubular mesoporous carbon composite consisting of FeS nanoparticles and tubular mesoporous carbon (CMK-5) is synthesized as anode material for Li- and Na-ions batteries. For applications in Li-ion batteries, the FeS@CMK-5 anode maintains a high reversible capacity of 720 mAh g(-1) after 100 cycles at 200 mAg(-1), much better than that of pristine FeS (166 mAh g(-1)) and CMK-5 (472 mAh g(-1)). Na-ion storage measurements reveal that the FeS@CMK-5 composite delivers a reversible capacity of 445 and 391 mAh g(-1), respectively, at the current density of 1000 and 5000 mA g(-1) over 100 cycles. The excellent electrochemical properties of FeS@CMK-5 for Li- and Na-ions storage can be attributed to its special structural superiority, which effectively accommodates the volume change, improves the electrical conductivity, and shortens the diffusion paths of Li- and Na-ions during the insertion/extraction process. (C) 2019 Published by Elsevier B.V.