Synthesis and optical properties of 2,13-dibenzothiazol-2′-yldibenzo[b,k]-18-crown-6

被引：1
|
作者：
Huang Zhi-Bin [1 ]
Kim Sung-Hong [2 ]
Shi Da-Qing [1 ]
Kang Tai-Jong [3 ]
Chang Seung-Hyun [3 ]
机构：
[1] Suzhou Univ, Coll Chem & Chem Engn, Suzhou 215123, Jiangsu, Peoples R China
[2] Korea Basic Sci Inst, Anal Res Div, Taegu 702701, South Korea
[3] Daegu Univ, Dept Chem, Kyongbuk 712714, South Korea
来源：
CHINESE JOURNAL OF CHEMISTRY | 2008年 / 26卷 / 06期
关键词：
crown ether; absorption spectra; fluorescence spectra;
D O I：
10.1002/cjoc.200890194
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new crown ether of 2,13-dibenzothiazol-2'-yldibenzo[b,k]-18-crown-6 was synthesized from 2,13-diformyldibenzo[b,k]-18-crown-6 with 2-aminothiophenol. The binding behavior and the optical properties of the crown ether were examined through UV-visible spectroscopy and fluorescence spectroscopy. When complexed with Na+, K+, Rb+ and Cs+ ions, it led to intramolecular charge transfer and caused the changes of the fluorescence spectra. The protonation of the crown ether was also studied.
引用
收藏
页码：1096 / 1100
页数：5
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