Selective formation of a two-dimensional coordination polymer based on a tridentate phospholane ligand and gold(I)

被引：8
|
作者：
Hoy, Reinhard [1 ]
Loennecke, Peter [1 ]
Hey-Hawkins, Evamarie [1 ]
机构：
[1] Univ Leipzig, Inst Inorgan Chem, Fac Chem & Mineral, D-04103 Leipzig, Germany
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 41期
关键词：
CRYSTAL-STRUCTURE; COMPLEXES; LUMINESCENT; AU; 3-COORDINATE; AU(I); AG; TETRAHEDRA; PHOSPHINES; CHEMISTRY;
D O I：
10.1039/c8dt03630f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The tridentate phosphine ligand 1,3,5-tris[(E)-(4-phospholano-2,6-diethyl)styryl]benzene (1) reacts with [AuCl(tht)] (tht = tetrahydrothiophene) independent of the stoichiometry employed with selective formation of a two-dimensional coordination polymer (ratio 1 : 1) with the gold(I) cations in a trigonal-planar [3 + 1] coordination geometry. Each of the three coordinating phosphine units originates from another ligand, thus forming a polymeric structure.
引用
收藏
页码：14515 / 14520
页数：6
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