Greener synthesis of new ammonium ionic liquids and their potential as extracting agents

被引：99
|
作者：
Kogelnig, Daniel [1 ]
Stojanovic, Anja [1 ]
Galanski, Mathea S. [1 ]
Groessl, Michael [1 ]
Iirsa, Franz [1 ]
Krachler, Regina [1 ]
Keppler, Bernhard K. [1 ]
机构：
[1] Univ Vienna, Inst Inorgan Chem, Waehringer Str 42, A-1090 Vienna, Austria
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 17期
关键词：
D O I：
10.1016/j.tetlet.2008.02.138
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New hydrophobic ionic liquids were synthesized from tricaprylmethylammonium chloride (Aliquat 336 (c)) and selected Bronsted acids by a sustainable, simple and cost-saving deprotonation-metathesis route. Prepared ionic liquids were evaluated as potential extracting agents for cadmium from different aqueous solutions. High efficiency and selectivity were reached for the extraction of cadmium from a natural river matrix with tricaprylmethylammonium thiosalicylate, [A336][TS], a thiol-containing task specific ionic liquid. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2782 / 2785
页数：4
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