A generalized correlation for the second virial coefficient based upon the Stockmayer potential

被引:0
|
作者
Ramos-Estrada, M [1 ]
Tellez-Morales, R
Iglesias-Silva, GA
Hall, KR
机构
[1] Inst Tecnol Celaya, Dto Ing Quim, Celaya 38010, Gto, Mexico
[2] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77843 USA
关键词
second virial coefficient; correlation; Stockmayer potential; Boyle temperature;
D O I
暂无
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
We have approximated the second virial coefficients obtained from the Stockmayer potential using a two parameter, analytical correlation. The correlation eliminates the need for integration of the potential over nearly the entire range of reduced temperatures. The equation is valid from 0 to 1.5 reduced dipole moment and uses the Boyle temperature as a normalizing variable. Because the equation is a correlation, the parameters do not necessarily have any physical meaning. We have applied the new equation to nonpolar compounds, aromatics, freons, alcohols, ethers, aldehydes, and acids.
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页码:41 / 47
页数:7
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