Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B5O8(OH)(H2O)x] NO3•2H2O [RE = Nd (x=0.85), Sm (x=0)]

被引：8
|
作者：
Ortner, Teresa S. [1 ]
Wurst, Klaus [1 ]
Joachim, Bastian [2 ]
Huppertz, Hubert [1 ]
机构：
[1] Leopold Franzens Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
[2] Leopold Franzens Univ Innsbruck, Inst Mineral & Petrog, Innrain 52, A-6020 Innsbruck, Austria
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2016年 / 22期
关键词：
Borate-nitrates; Rare earths; Hydrothermal synthesis; Crystal structure; BOND-VALENCE PARAMETERS; CENTER-DOT 2H(2)O; CRYSTAL-STRUCTURE; INFRARED-SPECTRA; HYDROGEN-BONDS; EARTH; SOLIDS; ION; ABSORPTION; GLASSES;
D O I：
10.1002/ejic.201600480
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The rare-earth borate-nitrates Nd[B5O8(OH)(H2O)(0.8)5]NO3 center dot 2H(2)O and Sm[B5O8(OH)]NO3 center dot 2H(2)O have been prepared by hydrothermal synthesis. Both structures crystallize monoclinically in the space group P2(1)/n (no. 14) with a = 642.85(2), b = 1552.58(4), c = 1070.52(2) pm, beta = 90.39(1)degrees, and V = 1068.44(5) nm(3) for the neodymium compound, and a = 644.09(3), b = 1541.99(8), c = 1050.97(5) pm, beta = 90.33(1)degrees, and V = 1043.79(9) nm(3) for the samarium variant. These compounds represent defect structures of Ce[B5O8(OH)(H2O)]NO3 center dot 2H(2)O. In addition to powder and single-crystal X-ray diffraction, the two novel borate-nitrates were characterized by IR and Raman spectroscopy.
引用
收藏
页码：3659 / 3665
页数：7
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