Synthesis of silica-supported poly-γ-diphenylarsinopropylsiloxane palladium complex and its catalytic behavior for Heck carbonylation of aryl halides

被引：24

作者：

Cai, MZ ^{[1
]}

Huang, YZ

Hu, RH

Song, CS

机构：

[1] Jiangxi Normal Univ, Dept Chem, Nanchang 330027, Peoples R China

[2] Jinggangshan Teachers Coll, Dept Chem, Jian 343009, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 208卷 / 1-2期

关键词：

supported palladium catalyst; arsenide palladium complex; aryl halide; Heck carbonylation;

D O I：

10.1016/S1381-1169(03)00534-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A silica-supported poly-gamma-diphenylarsinopropylsiloxane palladium complex has been prepared from gamma-chloropropyltriethoxysilane via immobilization on fumed silica, followed by reacting with potassium diphenylarsenide in THF and then the reaction with palladium chloride. It is an efficient catalyst for Heck carbonylation of aryl halides under atmospheric pressure of carbon monoxide. This polymeric palladium catalyst can be recovered and reused. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：17 / 20

页数：4

共 50 条

[1] Silica-supported poly-γ-methylselenopropylsiloxane palladium complex -: An efficient catalyst for Heck carbonylation of aryl halides
Cai, MZ
Zhou, J
Zhao, H
Song, CS
REACTIVE & FUNCTIONAL POLYMERS, 2002, 50 (02): : 191 - 195
[2] Silica-supported poly-γ-methylselenopropylsiloxane palladium complex: An efficient catalyst for Heck carbonylation of aryl halides
Mingzhong, Cai
Jun, Zhou
Hong, Zhao
Caisheng, Song
2002, Elsevier (50)
[3] Synthesis of silica-supported poly-γ-diphenylarsinopropylsiloxane palladium(0) complex and its catalytic properties for Heck arylation of conjugated alkenes
Cai, MZ
Huang, YZ
Zhao, H
Song, CS
REACTIVE & FUNCTIONAL POLYMERS, 2004, 59 (01): : 81 - 86
[4] Synthesis of silica-supported poly-ω-(methylseleno)undecylsiloxane palladium(0) complex and its catalytic properties for Heck arylation of alkenes
Cai, MZ
Gang, L
Jun, Z
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 227 (1-2) : 107 - 111
[5] Carbonyl allylation of aldehydes catalyzed by a silica-supported poly-γ-diphenylarsinopropylsiloxane palladium(0) complex
Cai, MZ
Huang, YH
Zhao, H
Zhang, RL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (15) : 2436 - 2440
[6] Synthesis of silica-supported bidentate arsine palladium complex and its catalytic properties for amidation/butoxycarbonylation of aryl halides
Cai, MZ
Huang, YZ
Hu, RH
Song, CS
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 212 (1-2) : 151 - 154
[7] Synthesis and catalytic characteristics of a silica-supported poly-ω-(methylseleno)undecylsiloxane palladium(0) complex
Liu, G
Zhang, RL
Cai, MZ
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2006, 26 (02) : 215 - 218
[8] Carbonylation of aryl halides catalyzed by a silica-supported sulfur and phosphine mixed bidentate palladium complex
Cai, MZ
Zhao, H
Huang, YX
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 238 (1-2) : 41 - 45
[9] Formylation of aryl halides catalyzed by a silica-supported phosphine palladium complex
Cai, MZ
Zhao, H
Zhou, J
Song, CS
SYNTHETIC COMMUNICATIONS, 2002, 32 (06) : 923 - 926
[10] Synthesis of MCM-41-supported thioether palladium complex and its catalytic properties in carbonylation of aryl halides
Yu, La-Mei
Xu, Qiu-Hua
Cai, Ming-Zhong
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2008, 28 (02) : 256 - 260

← 1 2 3 4 5 →