Synthesis of Fluorinated Bent-Core Mesogens (BCMs) Containing the 1,2,4-Oxadiazole Ring

被引：7

作者：

Piccionello, Antonio Palumbo ^{[1
,2
]}

Calabrese, Alessandro ^{[3
]}

Pibiri, Ivana ^{[1
,2
]}

Giacalone, Valentina ^{[1
]}

Pace, Andrea ^{[1
,2
]}

Buscemi, Silvestre ^{[1
]}

机构：

[1] Univ Palermo, Dipartimento Sci & Tecnol Biol Chim & Farmaceut, Viale Sci,Ed 17, I-90128 Palermo, Italy

[2] IEMEST, Ist Euromediterraneo Sci & Tecnol, Via E Amari 123, I-90145 Palermo, Italy

[3] ENEA UTTRI Ufficio Terr Sicilia, Via Principe Granatelli 24, I-90139 Palermo, Italy

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2016年 / 53卷 / 06期

关键词：

LIQUID-CRYSTALS; HETEROCYCLIC-COMPOUNDS; BUILDING-BLOCKS; NEMATIC PHASE; DERIVATIVES; HYDRAZINE; 5-PERFLUOROALKYL-1,2,4-OXADIAZOLES; POLYASPARTAMIDE; OXADIAZOLES; MOLECULES;

D O I：

10.1002/jhet.2509

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New fluorinated bent-core mesogens containing the 1,2,4-oxadiazole or 1,2,4-triazole nucleus have been synthesized taking advantage of the ANRORC (Addition of Nucleophile, Ring-Opening, Ring-Closure) reactivity of 5-perfluoroalkyl-1,2,4-oxadiazoles. Physical state changes of the obtained compounds were characterized through DSC, POM, and SAXS. Besides the formation of a smectic mesophase, a novel behavior as organic molecular glass was evidenced for some 1,2,4-oxadiazole derivatives.

引用

页码：1935 / 1940

页数：6

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