Recent progress in metal-organic framework-based supercapacitor electrode materials

被引:392
作者
Xu, Ben [1 ,3 ]
Zhang, Haobing [2 ]
Mei, Hao [2 ]
Sun, Daofeng [1 ,2 ]
机构
[1] China Univ Petr East China, Sch Mat Sci & Engn, Qingdao 266580, Shandong, Peoples R China
[2] China Univ Petr East China, Coll Sci, Qingdao 266580, Shandong, Peoples R China
[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
关键词
Metal-organic frameworks; Derivatives; Supercapacitor electrodes; Recyclable MOF-hydrolyzing strategy; ELECTROCHEMICAL ENERGY-STORAGE; DOUBLE-HYDROXIDE NANOSHEETS; REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE; POROUS CARBON; NANOPOROUS CARBON; NANOWIRE ARRAYS; ION BATTERIES; ASYMMETRIC SUPERCAPACITORS; HOLLOW STRUCTURES;
D O I
10.1016/j.ccr.2020.213438
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Supercapacitors are important energy storage devices due to its fast charging/discharging features and long cycle life. Design and fabrication of superior supercapacitor electrodes is of significance to the improvement of the overall performances of a device. Metal-organic frameworks (MOFs) have been widely reported for supercapacitor applications due to their high-tunability, including favorable porous properties, tunable chemical compositions, controllable crystal structures, and adjustable geometry morphologies. In this review, the recent reports focusing on MOF-based supercapacitor applications are elaborated. Particularly, the recyclable MOF-hydrolyzing strategy is introduced, during which the organic ligands can be recollected to drastically reduce the costs. Furthermore, challenges and perspectives of MOFs for supercapacitor electrode applications are also summarized. (C) 2020 Elsevier B.V. All rights reserved.
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页数:22
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