Numerical Models for Ionic Conduction in CuBr-TiO2 Composites and for Electrolysis of CuBr Films

被引：3

作者：

Lambert, C. ^{[1
,3
]}

Memoli, L. ^{[1
]}

Debierre, J. -M. ^{[1
]}

Knauth, P. ^{[2
]}

Albinet, G. ^{[3
]}

机构：

[1] Fac Sci & Tech St Jerome, Lab MATOP, F-13397 Marseille 20, France

[2] Fac Sci & Tech St Jerome, Lab Physicochim Mat, F-13397 Marseille 20, France

[3] Fac Sci & Tech St Jerome, Lab IRPHE, F-13397 Marseille 20, France

来源：

IONICS | 1999年 / 5卷 / 3-4期

关键词：

D O I：

10.1007/BF02375840

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of size dispersion of CuBr grains on the experimentally observed conductivity enhancement in CuBr-TiO2 composites is investigated. Using an extension of a random resistor network model recently introduced, we show that a bimodal size distribution can be simulated using a mean size value. Furthermore, we develop an electric breakdown model to simulate dendritic decomposition structures observed near the copper electrodes when a certain voltage is applied to thin CuBr films. Preliminary results for homogeneous systems without conductivity gradient are presented.

引用

页码：200 / 205

页数：6

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