An open metal-organic framework based on Cu3-triad triangular units and templated by double Wells-Dawson anions

被引：19
|
作者：
Wang, Dan-dan [1 ]
Peng, Jun [1 ]
Zhang, Peng-peng [1 ]
Wang, Xiang [1 ]
Zhu, Min [1 ]
Liu, Ming-guan [1 ]
Meng, Cui-li [1 ]
Alimaje, Kundawlet [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Polyoxometalate; Double templates; Cu-3-triad triangular unit; Electrochemical property; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMER; BUILDING-BLOCKS; CATALYSIS; TRINUCLEAR; CHEMISTRY;
D O I：
10.1016/j.inoche.2011.09.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel double-Dawson-anion-templated, triangular trinuclear Cu-trz unit-based metal-organic framework [Cu-8(II)(trz)(6)(mu(3)-O)(2)(H2O)(12)][P2W18O62]center dot 4H(2)O (1) (Htrz=1,2,4-triazole), has been hydrothermally synthesized and characterized by routine methods. Compound 1 is the first example of the Cu-3-triad triangular unit-based three-dimensional (3D) metal-organic framework templated by double [P2W18O62](6-) polyoxoanions. Furthermore, the electrochemical property of compound 1 has been studied. (C) 2011 Published by Elsevier B.V.
引用
收藏
页码：1911 / 1914
页数：4
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