An open metal-organic framework based on Cu3-triad triangular units and templated by double Wells-Dawson anions

被引：19

作者：

Wang, Dan-dan ^{[1
]}

Peng, Jun ^{[1
]}

Zhang, Peng-peng ^{[1
]}

Wang, Xiang ^{[1
]}

Zhu, Min ^{[1
]}

Liu, Ming-guan ^{[1
]}

Meng, Cui-li ^{[1
]}

Alimaje, Kundawlet ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 12期

基金：

中国国家自然科学基金;

关键词：

Polyoxometalate; Double templates; Cu-3-triad triangular unit; Electrochemical property; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMER; BUILDING-BLOCKS; CATALYSIS; TRINUCLEAR; CHEMISTRY;

D O I：

10.1016/j.inoche.2011.09.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel double-Dawson-anion-templated, triangular trinuclear Cu-trz unit-based metal-organic framework [Cu-8(II)(trz)(6)(mu(3)-O)(2)(H2O)(12)][P2W18O62]center dot 4H(2)O (1) (Htrz=1,2,4-triazole), has been hydrothermally synthesized and characterized by routine methods. Compound 1 is the first example of the Cu-3-triad triangular unit-based three-dimensional (3D) metal-organic framework templated by double [P2W18O62](6-) polyoxoanions. Furthermore, the electrochemical property of compound 1 has been studied. (C) 2011 Published by Elsevier B.V.

引用

页码：1911 / 1914

页数：4

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